Room-temperature phosphorescent materials derived from natural resources.
Journal
Nature reviews. Chemistry
ISSN: 2397-3358
Titre abrégé: Nat Rev Chem
Pays: England
ID NLM: 101703631
Informations de publication
Date de publication:
Nov 2023
Nov 2023
Historique:
accepted:
15
08
2023
medline:
26
9
2023
pubmed:
26
9
2023
entrez:
25
9
2023
Statut:
ppublish
Résumé
Room-temperature phosphorescent (RTP) materials have enormous potential in many different areas. Additionally, the conversion of natural resources to RTP materials has attracted considerable attention. Owing to their inherent luminescent properties, natural materials can be efficiently converted into sustainable RTP materials. However, to date, only a few reviews have focused on this area of endeavour. Motivated by this lack of coverage, in this Review, we address this shortcoming and introduce the types of natural resource available for the preparation of RTP materials. We mainly focus on the inherent advantages of natural resources for RTP materials, strategies for activating and enhancing the RTP properties of the natural resources as well as the potential applications of these RTP materials. In addition, we discuss future challenges and opportunities in this area of research.
Identifiants
pubmed: 37749285
doi: 10.1038/s41570-023-00536-4
pii: 10.1038/s41570-023-00536-4
doi:
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
800-812Informations de copyright
© 2023. Springer Nature Limited.
Références
Zhao, W., He, Z. & Tang, B. Z. Room-temperature phosphorescence from organic aggregates. Nat. Rev. Mater. 5, 869–885 (2020).
doi: 10.1038/s41578-020-0223-z
Gao, R., Kodaimati, M. S. & Yan, D. Recent advances in persistent luminescence based on molecular hybrid materials. Chem. Soc. Rev. 50, 5564–5589 (2021).
pubmed: 33690765
doi: 10.1039/D0CS01463J
Ma, X., Wang, J. & Tian, H. Assembling-induced emission: an efficient approach for amorphous metal-free organic emitting materials with room-temperature phosphorescence. Acc. Chem. Res. 52, 738–748 (2019).
pubmed: 30816706
doi: 10.1021/acs.accounts.8b00620
Tang, S. et al. Nonconventional luminophores: characteristics, advancements and perspectives. Chem. Soc. Rev. 50, 12616–12655 (2021).
pubmed: 34610056
doi: 10.1039/D0CS01087A
Li, Q. & Li, Z. Molecular packing: another key point for the performance of organic and polymeric optoelectronic materials. Acc. Chem. Res. 53, 962–973 (2020).
pubmed: 32242656
doi: 10.1021/acs.accounts.0c00060
Nie, H., Wei, Z., Ni, X.-L. & Liu, Y. Assembly and applications of macrocyclic-confinement-derived supramolecular organic luminescent emissions from cucurbiturils. Chem. Rev. 122, 9032–9077 (2022).
pubmed: 35312308
doi: 10.1021/acs.chemrev.1c01050
Tian, R., Xu, S.-M., Xu, Q. & Lu, C. Large-scale preparation for efficient polymer-based room-temperature phosphorescence via click chemistry. Sci. Adv. 6, eaaz6107 (2020).
pubmed: 32671211
pmcid: 7314566
doi: 10.1126/sciadv.aaz6107
Liu, S., Lin, Y. & Yan, D. Hydrogen-bond organized 2D metal–organic microsheets: direct ultralong phosphorescence and color-tunable optical waveguides. Sci. Bull. 67, 2076–2084 (2022).
doi: 10.1016/j.scib.2022.09.025
Zhou, B. & Yan, D. Long persistent luminescence from metal–organic compounds: state of the art. Adv. Funct. Mater. 33, 2300735 (2023).
doi: 10.1002/adfm.202300735
Liu, S., Fang, X., Lu, B. & Yan, D. Wide range zero-thermal-quenching ultralong phosphorescence from zero-dimensional metal halide hybrids. Nat. Commun. 11, 4649 (2020).
pubmed: 32938942
pmcid: 7494901
doi: 10.1038/s41467-020-18482-w
Kumar, P., Singh, S. & Gupta, B. K. Future prospects of luminescent nanomaterial based security inks: from synthesis to anti-counterfeiting applications. Nanoscale 8, 14297–14340 (2016).
pubmed: 27424665
doi: 10.1039/C5NR06965C
Evans, R. C., Douglas, P. & Winscom, C. J. Coordination complexes exhibiting room-temperature phosphorescence: evaluation of their suitability as triplet emitters in organic light emitting diodes. Coord. Chem. Rev. 250, 2093–2126 (2006).
doi: 10.1016/j.ccr.2006.02.007
Feldmann, C., Jüstel, T., Ronda, C. R. & Schmidt, P. J. Inorganic luminescent materials: 100 years of research and application. Adv. Funct. Mater. 13, 511–516 (2003).
doi: 10.1002/adfm.200301005
Yan, Y., Zhang, J., Ren, L. & Tang, C. Metal-containing and related polymers for biomedical applications. Chem. Soc. Rev. 45, 5232–5263 (2016).
pubmed: 26910408
pmcid: 4996776
doi: 10.1039/C6CS00026F
Green, D. C. et al. Controlling the fluorescence and room-temperature phosphorescence behaviour of carbon nanodots with inorganic crystalline nanocomposites. Nat. Commun. 10, 206 (2019).
pubmed: 30643136
pmcid: 6331607
doi: 10.1038/s41467-018-08214-6
Zheng, X. et al. Nearly unity quantum yield persistent room-temperature phosphorescence from heavy atom-free rigid inorganic/organic hybrid frameworks. Angew. Chem. Int. Ed. Engl. 61, e202207104 (2022).
pubmed: 35674723
doi: 10.1002/anie.202207104
Yao, X. et al. Room-temperature phosphorescence enabled through nacre-mimetic nanocomposite design. Adv. Mater. 33, 2005973 (2021).
doi: 10.1002/adma.202005973
Wu, Z. et al. Persistent room temperature phosphorescence from triarylboranes: a combined experimental and theoretical study. Angew. Chem. Int. Ed. Engl. 59, 17137–17144 (2020).
pubmed: 32573931
pmcid: 7540320
doi: 10.1002/anie.202007610
Shao, W. & Kim, J. Metal-free organic phosphors toward fast and efficient room-temperature phosphorescence. Acc. Chem. Res. 55, 1573–1585 (2022).
pubmed: 35613040
doi: 10.1021/acs.accounts.2c00146
Hamzehpoor, E. et al. Efficient room-temperature phosphorescence of covalent organic frameworks through covalent halogen doping. Nat. Chem. 15, 83–90 (2023).
pubmed: 36302870
doi: 10.1038/s41557-022-01070-4
Ren, Y. et al. Clusterization-triggered color-tunable room-temperature phosphorescence from 1,4-dihydropyridine-based polymers. J. Am. Chem. Soc. 144, 1361–1369 (2022).
pubmed: 34937344
doi: 10.1021/jacs.1c11607
Jia, X. et al. Photoexcitation-controlled self-recoverable molecular aggregation for flicker phosphorescence. Proc. Natl Acad. Sci. USA 116, 4816–4821 (2019).
pubmed: 30796185
pmcid: 6421427
doi: 10.1073/pnas.1821991116
Wei, J. et al. Induction of strong long-lived room-temperature phosphorescence of N-phenyl-2-naphthylamine molecules by confinement in a crystalline dibromobiphenyl matrix. Angew. Chem. Int. Ed. Engl. 55, 15589–15593 (2016).
pubmed: 27862811
doi: 10.1002/anie.201607653
Ma, H., Peng, Q., An, Z., Huang, W. & Shuai, Z. Efficient and long-lived room-temperature organic phosphorescence: theoretical descriptors for molecular designs. J. Am. Chem. Soc. 141, 1010–1015 (2018).
doi: 10.1021/jacs.8b11224
Hirata, S. Molecular physics of persistent room temperature phosphorescence and long-lived triplet excitons. Appl. Phys. Rev. 9, 011304 (2022).
doi: 10.1063/5.0066613
Baryshnikov, G., Minaev, B. & Ågren, H. Theory and calculation of the phosphorescence phenomenon. Chem. Rev. 117, 6500–6537 (2017).
pubmed: 28388041
doi: 10.1021/acs.chemrev.7b00060
He, Z. et al. White light emission from a single organic molecule with dual phosphorescence at room temperature. Nat. Commun. 8, 416 (2017).
pubmed: 28871160
pmcid: 5583377
doi: 10.1038/s41467-017-00362-5
Fateminia, S. A. et al. Organic nanocrystals with bright red persistent room‐temperature phosphorescence for biological applications. Angew. Chem. Int. Ed. Engl. 129, 12328–12332 (2017).
doi: 10.1002/ange.201705945
Chen, C. et al. Intramolecular charge transfer controls switching between room temperature phosphorescence and thermally activated delayed fluorescence. Angew. Chem. Int. Ed. Engl. 130, 16645–16649 (2018).
doi: 10.1002/ange.201809945
Ye, W. et al. Confining isolated chromophores for highly efficient blue phosphorescence. Nat. Mater. 20, 1539–1544 (2021).
pubmed: 34426660
doi: 10.1038/s41563-021-01073-5
Zhu, T., Yang, T., Zhang, Q. & Yuan, W. Z. Clustering and halogen effects enabled red/near-infrared room temperature phosphorescence from aliphatic cyclic imides. Nat. Commun. 13, 2658 (2022).
pubmed: 35551197
pmcid: 9098632
doi: 10.1038/s41467-022-30368-7
Shoji, Y. et al. Unveiling a new aspect of simple arylboronic esters: long-lived room-temperature phosphorescence from heavy-atom-free molecules. J. Am. Chem. Soc. 139, 2728–2733 (2017).
pubmed: 28135418
doi: 10.1021/jacs.6b11984
Baroncini, M., Bergamini, G. & Ceroni, P. Rigidification or interaction-induced phosphorescence of organic molecules. Chem. Commun. 53, 2081–2093 (2017).
doi: 10.1039/C6CC09288H
Bolton, O., Lee, K., Kim, H.-J., Lin, K. Y. & Kim, J. Activating efficient phosphorescence from purely organic materials by crystal design. Nat. Chem. 3, 205–210 (2011).
pubmed: 21336325
doi: 10.1038/nchem.984
Yuan, W. Z. et al. Crystallization-induced phosphorescence of pure organic luminogens at room temperature. J. Phys. Chem. C 114, 6090–6099 (2010).
doi: 10.1021/jp909388y
Zhang, Z. Y., Chen, Y. & Liu, Y. Efficient room‐temperature phosphorescence of a solid‐state supramolecule enhanced by cucurbit [6] uril. Angew. Chem. Int. Ed. Engl. 58, 6028–6032 (2019).
pubmed: 30848043
doi: 10.1002/anie.201901882
Kwon, M. S., Lee, D., Seo, S., Jung, J. & Kim, J. Tailoring intermolecular interactions for efficient room-temperature phosphorescence from purely organic materials in amorphous polymer matrices. Angew. Chem. Int. Ed. Engl. 53, 11177–11181 (2014).
pubmed: 25044368
doi: 10.1002/anie.201404490
Jiang, K. et al. Triple‐mode emission of carbon dots: applications for advanced anti‐counterfeiting. Angew. Chem. Int. Ed. Engl. 55, 7231–7235 (2016).
pubmed: 27135645
doi: 10.1002/anie.201602445
Ma, X., Xu, C., Wang, J. & Tian, H. Amorphous pure organic polymers for heavy-atom-free efficient room-temperature phosphorescence emission. Angew. Chem. Int. Ed. Engl. 57, 10854–10858 (2018).
pubmed: 29719096
doi: 10.1002/anie.201803947
Gu, L. et al. Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer. Nat. Commun. 11, 944 (2020).
pubmed: 32071308
pmcid: 7029031
doi: 10.1038/s41467-020-14792-1
Kuila, S. & George, S. J. Phosphorescence energy transfer: ambient afterglow fluorescence from water‐processable and purely organic dyes via delayed sensitization. Angew. Chem. Int. Ed. Engl. 59, 9393–9397 (2020).
pubmed: 32142188
doi: 10.1002/anie.202002555
Li, D. et al. Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color. Nat. Commun. 13, 347 (2022).
pubmed: 35039504
pmcid: 8764117
doi: 10.1038/s41467-022-28011-6
Tao, S. et al. Design of metal‐free polymer carbon dots: a new class of room‐temperature phosphorescent materials. Angew. Chem. Int. Ed. Engl. 57, 2393–2398 (2018).
pubmed: 29356331
doi: 10.1002/anie.201712662
Gan, N., Shi, H., An, Z. & Huang, W. Recent advances in polymer‐based metal‐free room‐temperature phosphorescent materials. Adv. Funct. Mater. 28, 1802657 (2018).
doi: 10.1002/adfm.201802657
Nidhankar, A. D., Wakchaure, V. C. & Babu, S. S. Efficient metal-free organic room temperature phosphors. Chem. Sci. 12, 4216–4236 (2021).
pubmed: 34163691
pmcid: 8179585
doi: 10.1039/D1SC00446H
Chen, X. et al. Versatile room-temperature-phosphorescent materials prepared from N-substituted naphthalimides: emission enhancement and chemical conjugation. Angew. Chem. Int. Ed. Engl. 55, 9872–9876 (2016).
pubmed: 27385550
doi: 10.1002/anie.201601252
Feng, S. et al. Light/force-sensitive 0d lead-free perovskites: from highly efficient blue afterglow to white phosphorescence with near-unity quantum efficiency. Angew. Chem. Int. Ed. Engl. 61, e202116511 (2022).
pubmed: 35015323
doi: 10.1002/anie.202116511
Hirata, S. et al. Efficient persistent room temperature phosphorescence in organic amorphous materials under ambient conditions. Adv. Funct. Mater. 23, 3386–3397 (2013).
doi: 10.1002/adfm.201203706
Lei, Y. et al. Wide‐range color‐tunable organic phosphorescence materials for printable and writable security inks. Angew. Chem. Int. Ed. Engl. 59, 16054–16060 (2020).
pubmed: 32500576
doi: 10.1002/anie.202003585
Xiao, F. et al. Guest–host doped strategy for constructing ultralong-lifetime near-infrared organic phosphorescence materials for bioimaging. Nat. Commun. 13, 186 (2022).
pubmed: 35013474
pmcid: 8748955
doi: 10.1038/s41467-021-27914-0
Zhang, J. et al. Stimuli-responsive deep-blue organic ultralong phosphorescence with lifetime over 5 s for reversible water-jet anti-counterfeiting printing. Angew. Chem. Int. Ed. Engl. 60, 17094–17101 (2021).
pubmed: 34002451
doi: 10.1002/anie.202104361
Kaschuk, J. J. et al. Plant-based structures as an opportunity to engineer optical functions in next-generation light management. Adv. Mater. 34, 2104473 (2022).
doi: 10.1002/adma.202104473
Guo, X. et al. A sustainable wood-based iron photocatalyst for multiple uses with sunlight: water treatment and radical photopolymerization. Angew. Chem. Int. Ed. Engl. 62, e202301242 (2023).
pubmed: 36916463
doi: 10.1002/anie.202301242
Wan, K. et al. Structural materials with afterglow room temperature phosphorescence activated by lignin oxidation. Nat. Commun. 13, 5508 (2022). Structural RTP materials are prepared from natural wood via lignin oxidation.
pubmed: 36127373
pmcid: 9489714
doi: 10.1038/s41467-022-33273-1
Yang, M. et al. Repurposing lignin to generate functional afterglow paper. Cell Rep. Phys. Sci. 3, 100867 (2022).
doi: 10.1016/j.xcrp.2022.100867
Wang, X. et al. Lignin nanoparticles: promising sustainable building blocks of photoluminescent and haze films for improving efficiency of solar cells. ACS Appl. Mater. Interfaces 13, 33536–33545 (2021).
pubmed: 34251791
doi: 10.1021/acsami.1c08209
Zhang, Y. et al. Cross-linked polyphosphazene nanospheres boosting long-lived organic room-temperature phosphorescence. J. Am. Chem. Soc. 144, 6107–6117 (2022). Ellagic acid confined in the polymer matrix exhibits a strong RTP emission after chemical modification.
pubmed: 35316063
doi: 10.1021/jacs.2c02076
Wan, K. et al. Sustainable afterglow room-temperature phosphorescence emission materials generated using natural phenolics. Angew. Chem. Int. Ed. Engl. 61, e202202760 (2022). Natural phenolics exhibit RTP emission when they are trapped in a polymer matrix.
pubmed: 35388962
doi: 10.1002/anie.202202760
Zhu, Z., Zeng, L., Li, W., Xu, W. & Tian, D. Efficient persistent luminescence from cellulose–halide mixtures for optical encryption. ACS Sustain. Chem. Eng. 10, 16752–16759 (2022).
doi: 10.1021/acssuschemeng.2c05046
Zhang, X. et al. Ultralong phosphorescence cellulose with excellent anti-bacterial, water-resistant and ease-to-process performance. Nat. Commun. 13, 1117 (2022). Cellulose is efficiently converted to multifunctional RTP materials via chemical modifications.
pubmed: 35236853
pmcid: 8891296
doi: 10.1038/s41467-022-28759-x
Dou, X. et al. Clustering-triggered emission and persistent room temperature phosphorescence of sodium alginate. Biomacromolecules 19, 2014–2022 (2018).
pubmed: 29558794
doi: 10.1021/acs.biomac.8b00123
Lü, B. et al. Natural ultralong hemicelluloses phosphorescence. Cell Rep. Phys. Sci. 3, 101015 (2022). RTP emission is observed from natural hemicellulose in a solid state.
doi: 10.1016/j.xcrp.2022.101015
Nie, F. & Yan, D. Macroscopic assembly of chiral hydrogen-bonded metal-free supramolecular glasses for enhanced color-tunable ultralong room temperature phosphorescence. Angew. Chem. Int. Ed. Engl. 62, e202302751 (2023).
pubmed: 37170931
doi: 10.1002/anie.202302751
Nie, F., Wang, K.-Z. & Yan, D. Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal–organic complexes. Nat. Commun. 14, 1654 (2023). Supramolecular glasses with circularly polarized RTP emissions are fabricated using zinc(II) ion and chiral l-histidine.
pubmed: 36964159
pmcid: 10039082
doi: 10.1038/s41467-023-37331-0
Sun, Y. et al. Ultralong lifetime and efficient room temperature phosphorescent carbon dots through multi-confinement structure design. Nat. Commun. 11, 5591 (2020). Carbon dots with long-lived RTP emission are made from rice husk using a multiple confinement strategy.
pubmed: 33154386
pmcid: 7645781
doi: 10.1038/s41467-020-19422-4
Zhai, Y. et al. Room temperature phosphorescence from natural wood activated by external chloride anion treatment. Nat. Commun. 14, 2614 (2023). Natural wood is converted to RTP materials via external chloride anion treatment.
pubmed: 37147300
pmcid: 10162966
doi: 10.1038/s41467-023-37762-9
Habibi, Y., Lucia, L. A. & Rojas, O. J. Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem. Rev. 110, 3479–3500 (2010).
pubmed: 20201500
doi: 10.1021/cr900339w
Li, T. et al. Developing fibrillated cellulose as a sustainable technological material. Nature 590, 47–56 (2021).
pubmed: 33536649
doi: 10.1038/s41586-020-03167-7
Wang, S. et al. Strong, tough, ionic conductive, and freezing-tolerant all-natural hydrogel enabled by cellulose–bentonite coordination interactions. Nat. Commun. 13, 3408 (2022).
pubmed: 35729107
pmcid: 9213515
doi: 10.1038/s41467-022-30224-8
Zhao, D. et al. Cellulose-based flexible functional materials for emerging intelligent electronics. Adv. Mater. 33, 2000619 (2021).
doi: 10.1002/adma.202000619
Qin, Y. et al. Stretchable triboelectric self-powered sweat sensor fabricated from self-healing nanocellulose hydrogels. Adv. Funct. Mater. 32, 2201846 (2022).
doi: 10.1002/adfm.202201846
Chen, W. et al. Nanocellulose: a promising nanomaterial for advanced electrochemical energy storage. Chem. Soc. Rev. 47, 2837–2872 (2018).
pubmed: 29561005
doi: 10.1039/C7CS00790F
Tu, H., Zhu, M., Duan, B. & Zhang, L. Recent progress in high-strength and robust regenerated cellulose materials. Adv. Mater. 33, 2000682 (2021).
doi: 10.1002/adma.202000682
Liu, W. et al. Cellulose nanopaper: fabrication, functionalization, and applications. Nano-Micro Lett. 14, 104 (2022).
doi: 10.1007/s40820-022-00849-x
Zhang, X. et al. Cellulose-based ultralong room-temperature phosphorescence nanomaterials with tunable color and high quantum yield via nano-surface confining effect. Research 6, 0029 (2023).
pubmed: 37040512
pmcid: 10076006
doi: 10.34133/research.0029
Rao, J., Lv, Z., Chen, G. & Peng, F. Hemicellulose: structure, chemical modification, and application. Prog. Polym. Sci. 140, 101675 (2023).
doi: 10.1016/j.progpolymsci.2023.101675
Ibn Yaich, A., Edlund, U. & Albertsson, A.-C. Transfer of biomatrix/wood cell interactions to hemicellulose-based materials to control water interaction. Chem. Rev. 117, 8177–8207 (2017).
pubmed: 28581716
doi: 10.1021/acs.chemrev.6b00841
Qaseem, M. F., Shaheen, H. & Wu, A.-M. Cell wall hemicellulose for sustainable industrial utilization. Renew. Sust. Energ. Rev. 144, 110996 (2021).
doi: 10.1016/j.rser.2021.110996
Questell-Santiago, Y. M., Galkin, M. V., Barta, K. & Luterbacher, J. S. Stabilization strategies in biomass depolymerization using chemical functionalization. Nat. Rev. Chem. 4, 311–330 (2020).
pubmed: 37127959
doi: 10.1038/s41570-020-0187-y
Hao, X. et al. Dialdehyde xylan-based sustainable, stable, and catalytic liquid metal nano-inks. Green Chem. 23, 7796–7804 (2021).
doi: 10.1039/D1GC02696H
Bai, L. et al. Nanochitin: chemistry, structure, assembly, and applications. Chem. Rev. 122, 11604–11674 (2022).
pubmed: 35653785
pmcid: 9284562
doi: 10.1021/acs.chemrev.2c00125
Chen, Y. et al. Super-strong and super-stiff chitosan filaments with highly ordered hierarchical structure. Adv. Funct. Mater. 31, 2104368 (2021).
doi: 10.1002/adfm.202104368
Mohan, K. et al. Recent insights into the extraction, characterization, and bioactivities of chitin and chitosan from insects. Trends Food Sci. Technol. 105, 17–42 (2020).
pubmed: 32901176
pmcid: 7471941
doi: 10.1016/j.tifs.2020.08.016
Kumar, M. N. V. R., Muzzarelli, R. A. A., Muzzarelli, C., Sashiwa, H. & Domb, A. J. Chitosan chemistry and pharmaceutical perspectives. Chem. Rev. 104, 6017–6084 (2004).
pubmed: 15584695
doi: 10.1021/cr030441b
Avcu, E. et al. Electrophoretic deposition of chitosan-based composite coatings for biomedical applications: a review. Prog. Mater. Sci. 103, 69–108 (2019).
doi: 10.1016/j.pmatsci.2019.01.001
Kim, T.-H. et al. Chemical modification of chitosan as a gene carrier in vitro and in vivo. Prog. Polym. Sci. 32, 726–753 (2007).
doi: 10.1016/j.progpolymsci.2007.05.001
Sashiwa, H. & Aiba, S.-I. Chemically modified chitin and chitosan as biomaterials. Prog. Polym. Sci. 29, 887–908 (2004).
doi: 10.1016/j.progpolymsci.2004.04.001
Haridevan, H., Evans, D. A., Ragauskas, A. J., Martin, D. J. & Annamalai, P. K. Valorisation of technical lignin in rigid polyurethane foam: a critical evaluation on trends, guidelines and future perspectives. Green Chem. 23, 8725–8753 (2021).
doi: 10.1039/D1GC02744A
Kim, J., Nguyen, T. V. T., Kim, Y. H., Hollmann, F. & Park, C. B. Lignin as a multifunctional photocatalyst for solar-powered biocatalytic oxyfunctionalization of C-H bonds. Nat. Syn. 1, 217–226 (2022).
doi: 10.1038/s44160-022-00035-2
Bertella, S. & Luterbacher, J. S. Lignin functionalization for the production of novel materials. Trends Chem. 2, 440–453 (2020).
doi: 10.1016/j.trechm.2020.03.001
Ai, Y. et al. Toward cleaner production of nanocellulose: a review and evaluation. Green Chem. 24, 6406–6434 (2022).
doi: 10.1039/D2GC01669A
Vigh, M. A trashed treasure: lignin could become a large and renewable source of organic compounds for the chemical industry to replace fossil fuel‐based chemicals. EMBO Rep. 24, e57103 (2023).
pubmed: 36947364
doi: 10.15252/embr.202357103
Dai, L. et al. All-lignin-based hydrogel with fast pH-stimuli responsiveness for mechanical switching and actuation. Chem. Mater. 32, 4324–4330 (2020).
doi: 10.1021/acs.chemmater.0c01198
Sun, Z., Fridrich, B., de Santi, A., Elangovan, S. & Barta, K. Bright side of lignin eepolymerization: toward new platform chemicals. Chem. Rev. 118, 614–678 (2018).
pubmed: 29337543
pmcid: 5785760
doi: 10.1021/acs.chemrev.7b00588
Li, H., Bunrit, A., Li, N. & Wang, F. Heteroatom-participated lignin cleavage to functionalized aromatics. Chem. Soc. Rev. 49, 3748–3763 (2020).
pubmed: 32458909
doi: 10.1039/D0CS00078G
Wang, M. et al. Carbon modification of nickel catalyst for depolymerization of oxidized lignin to aromatics. ACS Catal. 8, 1614–1620 (2018).
doi: 10.1021/acscatal.7b03475
Shuai, L. et al. Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization. Science 354, 329–333 (2016).
pubmed: 27846566
doi: 10.1126/science.aaf7810
Wu, X. et al. Photocatalytic transformations of lignocellulosic biomass into chemicals. Chem. Soc. Rev. 49, 6198–6223 (2020).
pubmed: 32756629
doi: 10.1039/D0CS00314J
Zhang, T. et al. Stable lignin-based afterglow materials with ultralong phosphorescence lifetimes in solid-state and aqueous solution. Green Chem. 25, 1406–1416 (2023).
doi: 10.1039/D2GC04370J
Sileika, T. S., Barrett, D. G., Zhang, R., Lau, K. H. A. & Messersmith, P. B. Colorless multifunctional coatings inspired by polyphenols found in tea, chocolate, and wine. Angew. Chem. Int. Ed. Engl. 52, 10766–10770 (2013).
pubmed: 24027124
pmcid: 3933447
doi: 10.1002/anie.201304922
Haslam, E. Practical Polyphenolics: From Structure to Molecular Recognition and Physiological Action (Cambridge Univ. Press, 1998).
Bravo, L. Polyphenols: chemistry, dietary sources, metabolism, and nutritional significance. Nutr. Rev. 56, 317–333 (1998).
pubmed: 9838798
doi: 10.1111/j.1753-4887.1998.tb01670.x
Alara, O. R., Abdurahman, N. H. & Ukaegbu, C. I. Extraction of phenolic compounds: a review. Curr. Res. Food Sci. 4, 200–214 (2021).
pubmed: 33899007
pmcid: 8058613
doi: 10.1016/j.crfs.2021.03.011
Luo, W. et al. Engineering robust metal-phenolic network membranes for uranium extraction from seawater. Energy Environ. Sci. 12, 607–614 (2019).
doi: 10.1039/C8EE01438H
Qiu, X. et al. Superstructured mesocrystals through multiple inherent molecular interactions for highly reversible sodium ion batteries. Sci. Adv. 7, eabh3482 (2021).
pubmed: 34516887
pmcid: 8442931
doi: 10.1126/sciadv.abh3482
Geng, H. et al. Metal ion-directed functional metal-phenolic materials. Chem. Rev. 122, 11432–11473 (2022).
pubmed: 35537069
doi: 10.1021/acs.chemrev.1c01042
Yang, X. & Berglund, L. A. Structural and ecofriendly holocellulose materials from wood: microscale fibers and nanoscale fibrils. Adv. Mater. 33, 2001118 (2021).
doi: 10.1002/adma.202001118
Chen, C., Berglund, L., Burgert, I. & Hu, L. Wood nanomaterials and nanotechnologies. Adv. Mater. 33, 2006207 (2021).
doi: 10.1002/adma.202006207
Schubert, M., Panzarasa, G. & Burgert, I. Sustainability in wood products: a new perspective for handling natural diversity. Chem. Rev. 123, 1889–1924 (2022).
pubmed: 36535040
doi: 10.1021/acs.chemrev.2c00360
Ding, Y. et al. Emerging engineered wood for building applications. Chem. Rev. 123, 1843–1888 (2022).
pubmed: 36260771
doi: 10.1021/acs.chemrev.2c00450
Yuan, J. et al. Sustainable afterglow materials from lignin inspired by wood phosphorescence. Cell Rep. Phys. Sci. 2, 100542 (2021).
doi: 10.1016/j.xcrp.2021.100542
Fang, M.-M., Yang, J. & Li, Z. Recent advances in purely organic room temperature phosphorescence polymer. Chin. J. Polym. Sci. 37, 383–393 (2019).
doi: 10.1007/s10118-019-2218-z
Shokri, Z. et al. Elucidating the impact of enzymatic modifications on the structure, properties, and applications of cellulose, chitosan, starch and their derivatives: a review. Mater. Today Chem. 24, 100780 (2022).
doi: 10.1016/j.mtchem.2022.100780
Zhang, H. et al. Clusterization-triggered emission: uncommon luminescence from common materials. Mater. Today 32, 275–292 (2020).
doi: 10.1016/j.mattod.2019.08.010
Zhang, Z. et al. Modulating emission of boric acid into highly efficient and color-tunable afterglow via dehydration-induced through-pace conjugation. Adv. Sci. 10, 2300139 (2023).
doi: 10.1002/advs.202300139
Gao, Q. et al. Stereospecific redox-mediated clusterization reconstruction for constructing long-lived, color-tunable, and processable phosphorescence cellulose. Chem. Eng. J. 451, 138923 (2023).
doi: 10.1016/j.cej.2022.138923
Wang, Q. et al. Reevaluating protein photoluminescence: remarkable visible luminescence upon concentration and insight into the emission mechanism. Angew. Chem. Int. Ed. Engl. 131, 12797–12803 (2019). Clustering of the peptide backbone and pendant groups is proposed to be the reason for RTP emission of bovine serum albumin protein.
doi: 10.1002/ange.201906226
Gong, Y. et al. Room temperature phosphorescence from natural products: crystallization matters. Sci. China Chem. 56, 1178–1182 (2013). Efficient RTP is observed in natural compounds and polymers such as starch, cellulose, bovine serum albumin and other carbohydrates.
doi: 10.1007/s11426-013-4923-8
Zhu, Z., Zeng, L., Li, W., Tian, D. & Xu, W. Enhancing persistent luminescence of cellulose by dehydration for label-free time-resolved imaging. ACS Sustain. Chem. Eng. 9, 17420–17426 (2021). RTP from cellulose is used for label-free time-resolved imaging in plants.
doi: 10.1021/acssuschemeng.1c07358
Cai, S. et al. Ultralong organic phosphorescent foams with high mechanical strength. J. Am. Chem. Soc. 143, 16256–16263 (2021). RTP foams with strong mechanical performance are made from gelatin via freeze drying.
pubmed: 34550674
doi: 10.1021/jacs.1c07674
Zhang, X. et al. Irreversible humidity-responsive phosphorescence materials from cellulose for advanced anti-counterfeiting and environmental monitoring. ACS Appl. Mater. Interfaces 14, 16582–16591 (2022).
pubmed: 35357123
doi: 10.1021/acsami.2c00043
Du, L.-L. et al. Clustering-triggered emission of cellulose and its derivatives. Chin. J. Polym. Sci. 37, 409–415 (2019).
doi: 10.1007/s10118-019-2215-2
Zeng, L. et al. Luminescence lifetime tuning of non-conjugated organic clusters through external heavy-atom effect for smartphone-based time-resolved imaging. Chem. Eng. J. 460, 141452 (2023).
doi: 10.1016/j.cej.2023.141452
Jiang, J. et al. Tunable photoluminescence properties of microcrystalline cellulose with gradually changing crystallinity and crystal form. Macromol. Rapid Commun. 42, 2100321 (2021).
doi: 10.1002/marc.202100321
Guo, J., Yang, C. & Zhao, Y. Long-lived organic room-temperature phosphorescence from amorphous polymer systems. Acc. Chem. Res. 55, 1160–1170 (2022).
pubmed: 35394748
doi: 10.1021/acs.accounts.2c00038
Li, W. et al. Carbon dot-silica nanoparticle composites for ultralong lifetime phosphorescence imaging in tissue and cells at room temperature. Chem. Mater. 31, 9887–9894 (2019).
doi: 10.1021/acs.chemmater.9b04120
An, Z. et al. Stabilizing triplet excited states for ultralong organic phosphorescence. Nat. Mater. 14, 685–690 (2015).
pubmed: 25849370
doi: 10.1038/nmat4259
Wu, H. & Zhao, Y. Colour-tunable ultra-long emission. Nat. Photon. 13, 373–375 (2019).
doi: 10.1038/s41566-019-0447-x
Liu, R., Jiang, T., Liu, D. & Ma, X. A facile and green strategy to obtain organic room-temperature phosphorescence from natural lignin. Sci. China Chem. 65, 1100–1104 (2022).
doi: 10.1007/s11426-022-1228-0
Cho, K. G. et al. Light‐emitting devices based on electrochemiluminescence gels. Adv. Funct. Mater. 30, 1907936 (2020).
doi: 10.1002/adfm.201907936
Zeng, W. et al. Fiber‐based wearable electronics: a review of materials, fabrication, devices, and applications. Adv. Mater. 26, 5310–5336 (2014).
pubmed: 24943999
doi: 10.1002/adma.201400633
Kwon, S. et al. Recent progress of fiber shaped lighting devices for smart display applications — a fibertronic perspective. Adv. Mater. 32, 1903488 (2020).
doi: 10.1002/adma.201903488
Ge, M. et al. Luminescent materials derived from biomass resources. Coord. Chem. Rev. 477, 214951 (2023).
doi: 10.1016/j.ccr.2022.214951
Fu, Q. et al. Luminescent and hydrophobic wood films as optical lighting materials. ACS Nano 14, 13775–13783 (2020).
pubmed: 32986407
doi: 10.1021/acsnano.0c06110
Großkopf, J., Kratz, T., Rigotti, T. & Bach, T. Enantioselective photochemical reactions enabled by triplet energy transfer. Chem. Rev. 122, 1626–1653 (2022).
pubmed: 34227803
doi: 10.1021/acs.chemrev.1c00272
Dimitrios, B. Sources of natural phenolic antioxidants. Trends Food Sci. Technol. 17, 505–512 (2006).
doi: 10.1016/j.tifs.2006.04.004
Urakawa, K., Sumimoto, M., Arisawa, M., Matsuda, M. & Ishikawa, H. Redox switching of orthoquinone-containing aromatic compounds with hydrogen and oxygen gas. Angew. Chem. Int. Ed. Engl. 55, 7432–7436 (2016).
pubmed: 27145376
doi: 10.1002/anie.201601906
Kharissova, O. V., Dias, H. R., Kharisov, B. I., Pérez, B. O. & Pérez, V. M. J. The greener synthesis of nanoparticles. Trends Biotechnol. 31, 240–248 (2013).
pubmed: 23434153
doi: 10.1016/j.tibtech.2013.01.003
Daimon, T. et al. The silkworm Green b locus encodes a quercetin 5-O-glucosyltransferase that produces green cocoons with UV-shielding properties. Proc. Natl Acad. Sci. USA 107, 11471–11476 (2010).
pubmed: 20534444
pmcid: 2895092
doi: 10.1073/pnas.1000479107
Zou, C. et al. Bacterial cellulose: a versatile chiral host for circularly polarized luminescence. Molecules 24, 1008 (2019).
pubmed: 30871189
pmcid: 6471878
doi: 10.3390/molecules24061008
Liu, J., Kong, T. & Xiong, H. M. Mulberry-leaves-derived red-emissive carbon dots for feeding silkworms to produce brightly fluorescent silk. Adv. Mater. 34, 2200152 (2022).
doi: 10.1002/adma.202200152
Zhou, L. et al. Ultralong-lived up-conversional room-temperature afterglow materials with a polyvinyl alcohol substrate. Polymers 14, 2414 (2022).
pubmed: 35745990
pmcid: 9229245
doi: 10.3390/polym14122414
Zheng, Y. et al. Near-infrared-excited multicolor afterglow in carbon dots-based room-temperature afterglow materials. Angew. Chem. Int. Ed. Engl. 60, 22253–22259 (2021).
pubmed: 34390105
doi: 10.1002/anie.202108696
Liang, Y.-C. et al. Phosphorescent carbon-nanodots-assisted Förster resonant energy transfer for achieving red afterglow in an aqueous solution. ACS Nano 15, 16242–16254 (2021).
pubmed: 34623793
doi: 10.1021/acsnano.1c05234
Lin, F. et al. Stepwise energy transfer: near-infrared persistent luminescence from doped polymeric systems. Adv. Mater. 34, 2108333 (2022).
doi: 10.1002/adma.202108333
Wang, B. et al. Carbon dots in a matrix: energy-transfer-enhanced room-temperature red phosphorescence. Angew. Chem. Int. Ed. Engl. 58, 18443–18448 (2019).
pubmed: 31599051
doi: 10.1002/anie.201911035
Li, W., Chen, Z., Yu, H., Li, J. & Liu, S. Wood‐derived carbon materials and light‐emitting materials. Adv. Mater. 33, 2000596 (2021).
doi: 10.1002/adma.202000596
Zhang, X. et al. Natural‐product‐derived carbon dots: from natural products to functional materials. ChemSusChem 11, 11–24 (2018).
pubmed: 29072348
doi: 10.1002/cssc.201701847
Wang, P. et al. Producing long afterglow by cellulose confinement effect: a wood-inspired design for sustainable phosphorescent materials. Carbon 171, 946–952 (2021).
doi: 10.1016/j.carbon.2020.09.060
Song, Z. et al. A molecular engineering strategy for achieving blue phosphorescent carbon dots with outstanding efficiency above 50%. Adv. Mater. 35, 2207970 (2023).
doi: 10.1002/adma.202207970
Wang, B. & Lu, S. The light of carbon dots: from mechanism to applications. Matter 5, 110–149 (2022).
doi: 10.1016/j.matt.2021.10.016
Sun, Y.-P. et al. Quantum-sized carbon dots for bright and colorful photoluminescence. J. Am. Chem. Soc. 128, 7756–7757 (2006).
pubmed: 16771487
doi: 10.1021/ja062677d
Xu, X. et al. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments. J. Am. Chem. Soc. 126, 12736–12737 (2004).
pubmed: 15469243
doi: 10.1021/ja040082h
Liu, F., Li, Z., Li, Y., Feng, Y. & Feng, W. Room-temperature phosphorescent fluorine–nitrogen co-doped carbon dots: information encryption and anti-counterfeiting. Carbon 181, 9–15 (2021).
doi: 10.1016/j.carbon.2021.05.023
Wu, Q. et al. Chitosan-derived carbon dots with room-temperature phosphorescence and energy storage enhancement properties. ACS Sustain. Chem. Eng. 10, 3027–3036 (2022).
doi: 10.1021/acssuschemeng.1c08299
Shi, J. et al. Prepared carbon dots from wheat straw for detection of Cu
doi: 10.1016/j.saa.2022.121597
Ni, Y. et al. Room-temperature phosphorescence based on chitosan carbon dots for trace water detection in organic solvents and anti-counterfeiting application. Dye Pigment. 197, 109923 (2022).
doi: 10.1016/j.dyepig.2021.109923
Gao, Y. et al. Matrix-free and highly efficient room-temperature phosphorescence of nitrogen-doped carbon dots. Langmuir 34, 12845–12852 (2018).
pubmed: 30346780
doi: 10.1021/acs.langmuir.8b00939
Li, S. et al. Sustainable silk-derived multimode carbon dots. Small 17, 2103623 (2021).
doi: 10.1002/smll.202103623
Zhai, Y. et al. Carbon dots confined in 3D polymer network: producing robust room temperature phosphorescence with tunable lifetimes. Chin. Chem. Lett. 33, 783–787 (2022).
doi: 10.1016/j.cclet.2021.08.075
Liu, P. et al. Biomimetic confined self-assembly of chitin nanocrystals. Nano Today 43, 101420 (2022).
doi: 10.1016/j.nantod.2022.101420
Xu, M. et al. Exploring the circular polarization capacity from chiral cellulose nanocrystal films for a photo-controlled chiral helix of supramolecular polymers. Angew. Chem. Int. Ed. Engl. 61, e202117042 (2022).
pubmed: 35132754
doi: 10.1002/anie.202117042
Xu, M. et al. Designing hybrid chiral photonic films with circularly polarized room-temperature phosphorescence. ACS Nano 14, 11130–11139 (2020).
pubmed: 32813496
doi: 10.1021/acsnano.0c02060
Wang, X. et al. Organic phosphors with bright triplet excitons for efficient X-ray-excited luminescence. Nat. Photon. 15, 187–192 (2021).
doi: 10.1038/s41566-020-00744-0
Song, S. Y. et al. Colorful triplet excitons in carbon nanodots for time delay lighting. Adv. Mater. 35, 2212286 (2023).
doi: 10.1002/adma.202212286
Wang, J. et al. Rhodium(I) complex-based polymeric nanomicelles in water exhibiting coexistent near-infrared phosphorescence imaging and anticancer activity in vivo. J. Am. Chem. Soc. 142, 2709–2714 (2020).
pubmed: 31999447
doi: 10.1021/jacs.9b11013