An innovative fluorescent probe for the detection of cyanide - enhanced sensitivity by controlling its electrostatic potential and suitable for applications such as cell imaging and food analysis.

Cyanide Electrostatic potential Fluorescence probe Sensitivity Theoretical calculations

Journal

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
ISSN: 1873-3557
Titre abrégé: Spectrochim Acta A Mol Biomol Spectrosc
Pays: England
ID NLM: 9602533

Informations de publication

Date de publication:
15 Jan 2024
Historique:
received: 17 05 2023
revised: 07 09 2023
accepted: 20 09 2023
medline: 8 11 2023
pubmed: 29 9 2023
entrez: 28 9 2023
Statut: ppublish

Résumé

As cyanide is a huge hazard to the environment and human health, the study of the method of detecting low concentrations of cyanide is of great significance. In general, materials with strong positive electrostatic properties can use electrostatic attraction to enrich anions in the water near the materials, then realize rapid detection of low concentration anions by fluorescent probes. In this paper, fluorescent probes PI-S, PI-I and PI-N with cyanide-specific recognition and different charges were synthesized to study the relationship between the charge effect of probes and the sensing sensitivity. Through the zeta potential test and the calculation of the surface electrostatic potential, the positive electricity of PI-S, PI-I and PI-N gradually increased, the ΔG < 0 of the adsorption process gradually decreased, CN

Identifiants

pubmed: 37769464
pii: S1386-1425(23)01128-9
doi: 10.1016/j.saa.2023.123443
pii:
doi:

Substances chimiques

Cyanides 0
Fluorescent Dyes 0
Anions 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

123443

Informations de copyright

Copyright © 2023 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Liangqiang Wu (L)

College of Chemistry, Jilin University, Changchun 130021, PR China.

Hai Xu (H)

College of Chemistry, Jilin University, Changchun 130021, PR China.

Meili Shen (M)

China-Japan Union Hospital of Jilin University, Changchun 130031, PR China.

Yapeng Li (Y)

College of Chemistry, Jilin University, Changchun 130021, PR China.

Qingbiao Yang (Q)

College of Chemistry, Jilin University, Changchun 130021, PR China. Electronic address: yangqb@jlu.edu.cn.

Yaoxian Li (Y)

College of Chemistry, Jilin University, Changchun 130021, PR China.

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Classifications MeSH