SERS Tracking Oxidative Stress on a Metalloporphyrin Framework by Vitamin C.


Journal

Analytical chemistry
ISSN: 1520-6882
Titre abrégé: Anal Chem
Pays: United States
ID NLM: 0370536

Informations de publication

Date de publication:
17 10 2023
Historique:
medline: 1 11 2023
pubmed: 4 10 2023
entrez: 4 10 2023
Statut: ppublish

Résumé

Accurate control of charge transfer is crucial to investigate the catalytic reaction mechanism of the biological oxidation process that biomedicine participates in. Herein, we have established an assembly model of metalloporphyrin framework (MPF) nanosheets as the active centers of biological enzymes. The introduction of Vitamin C (VC) into the MPF system can precisely modulate its content of charges. The surface-enhanced Raman scattering activity and peroxidase-like catalytic performance are enhanced simultaneously for the first time by manipulating the optimal molar ratio of an MPF to VC and the reaction sequence with target model molecules. We have confirmed that the formation of the intermediate of Fe(

Identifiants

pubmed: 37793058
doi: 10.1021/acs.analchem.3c02935
doi:

Substances chimiques

Ascorbic Acid PQ6CK8PD0R
Metalloporphyrins 0
Antioxidants 0
Vitamins 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

15333-15341

Auteurs

Qinhui Xie (Q)

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.
School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P. R. China.
College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, P. R. China.

Hao Liu (H)

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.

Sisi Wen (S)

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.

Xiaojun Wang (X)

School of Construction Machinery, Shandong Jiaotong University, Changqing University Science Park, Jinan 250357, P. R. China.

Wei Bing (W)

School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P. R. China.
Key Laboratory of Bionic Engineering, Ministry of Education, Jilin University, Changchun 130022, P. R. China.

Wei Ji (W)

College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, P. R. China.

Bing Zhao (B)

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.

Yukihiro Ozaki (Y)

School of Biological and Environmatal Sciences, Kwansei Gakuin University, 1-Gakuen-Uegahara, Sanda, Hyogo 669-1330, Japan.

Wei Song (W)

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.

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Classifications MeSH