Clustering Six Electrons within "Dawson-Like" Polyoxometalate: An Open Route toward Its Post-functionalization.
Metal-Metal Bonds
Polyoxometalates
Post-Functionalization
Structural Elucidation
Super-Reduction
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
04 Dec 2023
04 Dec 2023
Historique:
received:
24
08
2023
medline:
13
10
2023
pubmed:
13
10
2023
entrez:
13
10
2023
Statut:
ppublish
Résumé
Super-reduction of polyoxometalates (POMs) in solution is of fundamental interest for designing innovative energy storage systems. In this article, we show that the "Dawson-like" POM can undergo a disproportionation process during its massive electron uptake, leading to species containing three metal-metal bonds as evidenced by X-ray diffraction, multi-nuclear magnetic resonance spectroscopy (
Identifiants
pubmed: 37831589
doi: 10.1002/anie.202312457
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202312457Subventions
Organisme : Ecoles doctorales, Université Paris-Saclay
Organisme : CNRS EMERGENCE@INC2023
Organisme : Agence Nationale de la Recherche
ID : ANR-11-LABX-0039-grant
Informations de copyright
© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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