Structural and spectroscopic characterization of large boron heterocyclic radicals: Matrix infrared spectroscopy and quantum chemical calculations.
Journal
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
ISSN: 1873-3557
Titre abrégé: Spectrochim Acta A Mol Biomol Spectrosc
Pays: England
ID NLM: 9602533
Informations de publication
Date de publication:
15 Jan 2024
15 Jan 2024
Historique:
received:
10
08
2023
revised:
08
10
2023
accepted:
14
10
2023
medline:
20
10
2023
pubmed:
20
10
2023
entrez:
19
10
2023
Statut:
ppublish
Résumé
Six boron heterocyclic radicals with different conformations or configurations were synthesized in solid neon and identified by matrix isolation infrared spectroscopy as well as quantum-chemical calculations. The ground-state boron atom selectively attacks the C = C bond of cycloheptene forming η
Identifiants
pubmed: 37857070
pii: S1386-1425(23)01224-6
doi: 10.1016/j.saa.2023.123539
pii:
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
123539Informations de copyright
Copyright © 2023 Elsevier B.V. All rights reserved.
Déclaration de conflit d'intérêts
Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Jiwen Jian reports financial support was provided by National Natural Science Foundation of China. Jiwen Jian reports a relationship with Zhejiang Normal University that includes: employment.