Transition Metals-Based Water Splitting Electrocatalysts on Copper-Based Substrates: The Integral Role of Morphological Properties.
copper substrate
hydrogen evolution reaction
oxygen evolution reaction
water splitting
Journal
Chemical record (New York, N.Y.)
ISSN: 1528-0691
Titre abrégé: Chem Rec
Pays: United States
ID NLM: 101085550
Informations de publication
Date de publication:
19 Oct 2023
19 Oct 2023
Historique:
revised:
12
09
2023
received:
02
07
2023
medline:
20
10
2023
pubmed:
20
10
2023
entrez:
19
10
2023
Statut:
aheadofprint
Résumé
Electrocatalytic water splitting is a promising alternative to produce high purity hydrogen gas as the green substitute for renewable energy. Thus, development of electrocatalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are vital to improve the efficiency of the water splitting process particularly based on transition metals which has been explored extensively to replace the highly active electrocatalytic activity of the iridium and ruthenium metals-based electrocatalysts. In situ growth of the material on a conductive substrate has also been proven to have the capability to lower down the overpotential value significantly. On top of that, the presence of substrate has given a massive impact on the morphology of the electrocatalyst. Among the conductive substrates that have been widely explored in the field of electrochemistry are the copper based substrates mainly copper foam, copper foil and copper mesh. Copper-based substrates possess unique properties such as low in cost, high tensile strength, excellent conductor of heat and electricity, ultraporous with well-integrated hierarchical structure and non-corrosive in nature. In this review, the recent advancements of HER and OER electrocatalysts grown on copper-based substrates has been critically discussed, focusing on their morphology, design, and preparation methods of the nanoarrays.
Identifiants
pubmed: 37857549
doi: 10.1002/tcr.202300228
doi:
Types de publication
Journal Article
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202300228Informations de copyright
© 2023 The Chemical Society of Japan & Wiley-VCH GmbH.
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