Carbon-carbon bond activation by Mg, Al, and Zn complexes.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
18 Oct 2023
18 Oct 2023
Historique:
received:
30
06
2023
accepted:
13
09
2023
medline:
20
10
2023
pubmed:
20
10
2023
entrez:
20
10
2023
Statut:
epublish
Résumé
Examples of carbon-carbon bond activation reactions at Mg, Al, and Zn are described in this review. Several distinct mechanisms for C-C bond activation at these metals have been proposed, with the key C-C bond activation step occurring by (i) α-alkyl elimination, (ii) β-alkyl elimination, (iii) oxidative addition, or (iv) an electrocyclic reaction. Many of the known pathways involve an overall 2-electron redox process. Despite this, the direct oxidative addition of C-C bonds to these metals is relatively rare, instead most reactions occur through initial installation of the metal on a hydrocarbon scaffold (
Identifiants
pubmed: 37860653
doi: 10.1039/d3sc03336h
pii: d3sc03336h
pmc: PMC10583701
doi:
Types de publication
Journal Article
Review
Langues
eng
Pagination
11012-11021Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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