Unusual triterpenoids and steroids from Cipadessa baccifera and their biological activities.


Journal

Fitoterapia
ISSN: 1873-6971
Titre abrégé: Fitoterapia
Pays: Netherlands
ID NLM: 16930290R

Informations de publication

Date de publication:
Dec 2023
Historique:
received: 09 08 2023
revised: 18 10 2023
accepted: 19 10 2023
medline: 27 11 2023
pubmed: 23 10 2023
entrez: 22 10 2023
Statut: ppublish

Résumé

Five undescribed triterpenoids and steroids (1-5), as well as ten known compounds, were purified from the branches and leaves of Cipadessa baccifera. Notably, 1 and 2 are rare cipadesin-type limonoids with an unusual 8,30-epoxide ring and 1,8-ether linkage, respectively. Compound 5 possessed pregnane steroid skeleton with an uncommon 5/6/6/6/5-fused ring system. Their structures were constructed by extensive spectroscopic analysis (NMR, IR, UV, and HRESIMS), and their absolute configurations were confirmed by ECD calculations and quantum chemical calculations. All the isolates were in vitro assayed for their antimicrobial potentials against 6 pathogenic microorganisms and antiproliferation activities against five human cancer cell lines. As a result, compounds 5, 12, 13, and 14 exhibited moderate antibacterial activities (MIC: 25-50 μg/mL). Moreover, 5 showed cytotoxicity against five cancer cell lines with IC

Identifiants

pubmed: 37866424
pii: S0367-326X(23)00283-6
doi: 10.1016/j.fitote.2023.105708
pii:
doi:

Substances chimiques

Triterpenes 0
Steroids 0
Limonins 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

105708

Informations de copyright

Copyright © 2023. Published by Elsevier B.V.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare no conflict of interest.

Auteurs

De-Yu Zhang (DY)

State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, PR China; Natural Products Research Center of Guizhou Province, Guiyang 550014, PR China.

Han-Fei Liu (HF)

State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, PR China; Natural Products Research Center of Guizhou Province, Guiyang 550014, PR China.

Tai-Bai Jiang (TB)

State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, PR China.

Chao Chen (C)

State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, PR China; Natural Products Research Center of Guizhou Province, Guiyang 550014, PR China.

Hua-Yong Lou (HY)

State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, PR China; Natural Products Research Center of Guizhou Province, Guiyang 550014, PR China. Electronic address: loouhy@126.com.

Wei-Dong Pan (WD)

School of Pharmaceutical Sciences, Guizhou University, Guiyang 550025, PR China. Electronic address: wdpan@163.com.

Jin-Yu Li (JY)

State Key Laboratory of Functions and Applications of Medicinal Plants, Guizhou Medical University, Guiyang 550014, PR China; Natural Products Research Center of Guizhou Province, Guiyang 550014, PR China. Electronic address: lijinyu20080@126.com.

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Classifications MeSH