Remote Excitation of Tip-Enhanced Photoluminescence with a Parallel AgNW Coupler.


Journal

ACS omega
ISSN: 2470-1343
Titre abrégé: ACS Omega
Pays: United States
ID NLM: 101691658

Informations de publication

Date de publication:
17 Oct 2023
Historique:
received: 11 07 2023
accepted: 05 09 2023
medline: 23 10 2023
pubmed: 23 10 2023
entrez: 23 10 2023
Statut: epublish

Résumé

Tip-enhanced photoluminescence (TEPL) microscopy allows for the correlation of scanning probe microscopic images and photoluminescent spectra at the nanoscale level in a similar way to tip-enhanced Raman scattering (TERS) microscopy. However, due to the higher cross-section of fluorescence compared to Raman scattering, the diffraction-limited background signal generated by far-field excitation is a limiting factor in the achievable spatial resolution of TEPL. Here, we demonstrate a way to overcome this drawback by using remote excitation TEPL (RE-TEPL). With this approach, the excitation and detection positions are spatially separated, minimizing the far-field contribution. Two probe designs are evaluated, both experimentally and

Identifiants

pubmed: 37867716
doi: 10.1021/acsomega.3c04952
pmc: PMC10586305
doi:

Types de publication

Journal Article

Langues

eng

Pagination

38386-38393

Informations de copyright

© 2023 The Authors. Published by American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

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Auteurs

Wannes Peeters (W)

Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee B-3001, Belgium.

Shuichi Toyouchi (S)

Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee B-3001, Belgium.

Yasuhiko Fujita (Y)

Research Institute for Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST Chugoku), Kagamiyama 3-11-32, Higashi-hiroshima, Hiroshima 739-0046, Japan.

Mathias Wolf (M)

Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee B-3001, Belgium.

Beatrice Fortuni (B)

Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee B-3001, Belgium.

Eduard Fron (E)

Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee B-3001, Belgium.

Tomoko Inose (T)

Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
The HAKUBI Center for Advanced Research, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan.

Johan Hofkens (J)

Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee B-3001, Belgium.
Max Planck Institute for Polymer Research, Mainz 55128, Germany.

Takahiko Endo (T)

Department of Physics, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan.

Yasumitsu Miyata (Y)

Department of Physics, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan.

Hiroshi Uji-I (H)

Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee B-3001, Belgium.
Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
RIES, Hokkaido University, N20 W10, Kita-Ward, Sapporo 001-0020, Japan.

Classifications MeSH