Ultrasound-assisted extraction followed by liquid chromatography coupled to tandem mass spectrometry for the simultaneous determination of multiclass herbicides in soil.
Herbicides
Liquid chromatography
Sample preparation
Soil
Tandem mass spectrometry
Ultrasound-assisted extraction
Journal
Analytical and bioanalytical chemistry
ISSN: 1618-2650
Titre abrégé: Anal Bioanal Chem
Pays: Germany
ID NLM: 101134327
Informations de publication
Date de publication:
Dec 2023
Dec 2023
Historique:
received:
13
07
2023
accepted:
25
09
2023
revised:
19
09
2023
medline:
30
11
2023
pubmed:
23
10
2023
entrez:
23
10
2023
Statut:
ppublish
Résumé
An analytical methodology based on ultrasound-assisted extraction (UAE) followed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) has been developed for the identification and quantification of 9 authorized herbicides in soil (dimethenamid-P, imazamox, S-metolachlor, nicosulfuron, pendimethalin, prosulfuron, bentazone, terbuthylazine, and mesotrione). Preliminary experiments dealing with solvent extraction, the extraction technique, and herbicide response comparison in soil, with and without organic amendments, were carried out with the purpose of obtaining high sample throughput and sensitivity. UAE and the solvent mixture water:methanol demonstrated higher efficiency and they were selected as sample treatment and extraction solvent, respectively. Critical parameters affecting UAE were optimized by experimental design. In the present research, the extraction technique used in the official EPA microwave-assisted extraction (MAE) methodology (United States Environmental Protection Agency) and UAE optimized methodology were compared. The results indicated that the developed method showed better efficacy since microwave extraction gave very poor responses for nicosulfuron and prosulfuron. The temperature extraction was also optimized; room temperature was the most suitable to work with. Under the optimized conditions, the proposed UAE-LC-MS/MS method was assessed in terms of linearity (R
Identifiants
pubmed: 37870584
doi: 10.1007/s00216-023-04987-y
pii: 10.1007/s00216-023-04987-y
doi:
Substances chimiques
prosulfuron
NG7LE47J14
nicosulfuron
CG297D9264
Herbicides
0
metolachlor
X0I01K05X2
Methanol
Y4S76JWI15
Soil
0
Solvents
0
Water
059QF0KO0R
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
7197-7209Subventions
Organisme : European Chemical Society
ID : Sample Preparation Study Group
Organisme : European Chemical Society
ID : Network
Organisme : Ministerio de Ciencia, Innovación y Universidades
ID : Red Nacional para la Innovación en las Técnicas
Organisme : Ministerio de Educación y Formación Profesional
ID : Collaboration grant
Organisme : International Union of Pure and Applied Chemistry
ID : Greenness of official standard sample preparation
Organisme : Xunta de Galicia
ID : ED431 2020/06
Organisme : Xunta de Galicia
ID : ED481A
Organisme : Xunta de Galicia
ID : IN606A
Organisme : Xunta de Galicia
ID : IN607B 2022/15
Organisme : Fundación Banco Santander
ID : Grant for the initiation of USC Master's research
Informations de copyright
© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.
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