Tools to Evaluate the Eco-efficiency of Analytical Methods in the Context of Green and White Analytical Chemistry: A Review.

AGREE ESA GAPI Green analytical chemistry NEMI pharmaceutical analysis. white analytical chemistry

Journal

Current pharmaceutical design
ISSN: 1873-4286
Titre abrégé: Curr Pharm Des
Pays: United Arab Emirates
ID NLM: 9602487

Informations de publication

Date de publication:
2023
Historique:
received: 08 06 2023
accepted: 14 09 2023
medline: 23 11 2023
pubmed: 25 10 2023
entrez: 25 10 2023
Statut: ppublish

Résumé

The release of a product in the consumer market requires an analysis by quality control. This sector makes use of reliable analytical methods, by high performance liquid chromatography (HPLC), spectrophotometry in the ultraviolet and visible regions (UV-Vis), spectrophotometry in the infrared region (IR) or thin layer chromatography (TLC), for example, to reach a result. The analysis conditions of most of these analytical methods currently still use toxic reagents, generate a greater amount of waste, sample preparation has more steps, the need for instrumentation and consumables in greater quantity, generating a cost and impact on health and the environment greater than if there were adoption of the Green Analytical Chemistry (GAC) and the White Analytical Chemistry (WAC). The objective of this review is to show the relationship of analytical choices for current pharmaceutical analyzes with the GAC and the WAC. Analytical methods can be evaluated for greenness and whiteness using tools such as the National Environmental Method Index (NEMI), Eco-Scale Assessment (ESA), Analytical Greenness Metric (AGREE) and Green Analytical Procedure Index (GAPI). The use of NEMI, ESA, AGREE and GAPI tools brings the objective evidence needed to discuss the greenness and whiteness of an analytical method, leaving the subjective level. Furthermore, semi or quantitative data facilitate the choice of an analytical method and its conditions, when the target is the concern with eco-efficiency.

Sections du résumé

BACKGROUND BACKGROUND
The release of a product in the consumer market requires an analysis by quality control. This sector makes use of reliable analytical methods, by high performance liquid chromatography (HPLC), spectrophotometry in the ultraviolet and visible regions (UV-Vis), spectrophotometry in the infrared region (IR) or thin layer chromatography (TLC), for example, to reach a result. The analysis conditions of most of these analytical methods currently still use toxic reagents, generate a greater amount of waste, sample preparation has more steps, the need for instrumentation and consumables in greater quantity, generating a cost and impact on health and the environment greater than if there were adoption of the Green Analytical Chemistry (GAC) and the White Analytical Chemistry (WAC).
OBJECTIVE/METHODS OBJECTIVE
The objective of this review is to show the relationship of analytical choices for current pharmaceutical analyzes with the GAC and the WAC.
RESULTS RESULTS
Analytical methods can be evaluated for greenness and whiteness using tools such as the National Environmental Method Index (NEMI), Eco-Scale Assessment (ESA), Analytical Greenness Metric (AGREE) and Green Analytical Procedure Index (GAPI).
CONCLUSION CONCLUSIONS
The use of NEMI, ESA, AGREE and GAPI tools brings the objective evidence needed to discuss the greenness and whiteness of an analytical method, leaving the subjective level. Furthermore, semi or quantitative data facilitate the choice of an analytical method and its conditions, when the target is the concern with eco-efficiency.

Identifiants

pubmed: 37877508
pii: CPD-EPUB-135549
doi: 10.2174/0113816128266396231017072043
doi:

Types de publication

Review Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2442-2449

Informations de copyright

Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.net.

Auteurs

Aline Sinzervinch (A)

Department of Pharmacy, School of Pharmaceutical Sciences, Faculty of Pharmacy, Federal University of Goiás, Goiânia, Brazil.

Ieda Maria Sapateiro Torres (IMS)

Department of Pharmacy, School of Pharmaceutical Sciences, Faculty of Pharmacy, Federal University of Goiás, Goiânia, Brazil.

Ana Carolina Kogawa (AC)

Department of Pharmacy, School of Pharmaceutical Sciences, Faculty of Pharmacy, Federal University of Goiás, Goiânia, Brazil.

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Classifications MeSH