A stronger acceptor decreases the rates of charge transfer: ultrafast dynamics and on/off switching of charge separation in organometallic donor-bridge-acceptor systems.


Journal

Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951

Informations de publication

Date de publication:
25 Oct 2023
Historique:
received: 21 11 2022
accepted: 23 09 2023
medline: 27 10 2023
pubmed: 27 10 2023
entrez: 27 10 2023
Statut: epublish

Résumé

To unravel the role of driving force and structural changes in directing the photoinduced pathways in donor-bridge-acceptor (DBA) systems, we compared the ultrafast dynamics in novel DBAs which share a phenothiazine (PTZ) electron donor and a Pt(ii)

Identifiants

pubmed: 37886100
doi: 10.1039/d2sc06409j
pii: d2sc06409j
pmc: PMC10599469
doi:

Types de publication

Journal Article

Langues

eng

Pagination

11417-11428

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Alexander J Auty (AJ)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Paul A Scattergood (PA)

Department of Chemical Sciences, University of Huddersfield HD1 3DH UK.

Theo Keane (T)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Tao Cheng (T)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Guanzhi Wu (G)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Heather Carson (H)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

James Shipp (J)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Andrew Sadler (A)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Thomas Roseveare (T)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Igor V Sazanovich (IV)

Laser for Science Facility, Rutherford Appleton Laboratory, RCaH, STFC OX11 0QX UK.

Anthony J H M Meijer (AJHM)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Dimitri Chekulaev (D)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Paul I P Elliot (PIP)

Department of Chemical Sciences, University of Huddersfield HD1 3DH UK.

Mike Towrie (M)

Laser for Science Facility, Rutherford Appleton Laboratory, RCaH, STFC OX11 0QX UK.

Julia A Weinstein (JA)

Department of Chemistry, The University of Sheffield Sheffield S3 7HF UK Julia.Weinstein@Sheffield.ac.uk, a.meijer@sheffield.ac.uk.

Classifications MeSH