Direct Synthesis of N-formamides by Integrating Reductive Amination of Ketones and Aldehydes with CO
MFM-300(Cr)
N-formylation
Reductive amination
SXPD
ssNMR
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
01 Feb 2024
01 Feb 2024
Historique:
received:
08
10
2023
medline:
30
10
2023
pubmed:
30
10
2023
entrez:
29
10
2023
Statut:
ppublish
Résumé
Formamides are important feedstocks for the manufacture of many fine chemicals. State-of-the-art synthesis of formamides relies on the use of an excess amount of reagents, giving copious waste and thus poor atom-economy. Here, we report the first example of direct synthesis of N-formamides by coupling two challenging reactions, namely reductive amination of carbonyl compounds, particularly biomass-derived aldehydes and ketones, and fixation of CO
Identifiants
pubmed: 37899311
doi: 10.1002/chem.202303289
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202303289Subventions
Organisme : European Research Council
ID : 742401
Pays : International
Informations de copyright
© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.
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