Intrinsic spin shielding effect in platinum-rare-earth alloy boosts oxygen reduction activity.

electrocatalysis intermetallic compound oxygen reduction reaction rare-earth metal spin effect

Journal

National science review
ISSN: 2053-714X
Titre abrégé: Natl Sci Rev
Pays: China
ID NLM: 101633095

Informations de publication

Date de publication:
Sep 2023
Historique:
received: 27 06 2022
revised: 22 03 2023
accepted: 23 03 2023
medline: 30 10 2023
pubmed: 30 10 2023
entrez: 30 10 2023
Statut: epublish

Résumé

Oxygen reduction reactions (ORRs) involve a multistep proton-coupled electron process accompanied by the conversion of the apodictic spin configuration. Understanding the role of spin configurations of metals in the adsorption and desorption of oxygen intermediates during ORRs is critical for the design of efficient ORR catalysts. Herein, a platinum-rare-earth-metal-based alloy catalyst, Pt

Identifiants

DOI: 10.1093/nsr/nwad162 PMID: 37900058 PMC: PMC10600901
pubmed: 37900058
doi: 10.1093/nsr/nwad162
pii: nwad162
pmc: PMC10600901
doi:

Types de publication

Journal Article

Langues

eng

Pagination

nwad162

Informations de copyright

© The Author(s) 2023. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd.

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Auteurs

Siyuan Zhu (S)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Mingzi Sun (M)

Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China.

Bingbao Mei (B)

Shanghai Synchrotron Radiation Facility, Zhangjiang National Laboratory, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai201204, China.

Liting Yang (L)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Yuyi Chu (Y)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Zhaoping Shi (Z)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Jingsen Bai (J)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Xian Wang (X)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Zheng Jiang (Z)

Shanghai Synchrotron Radiation Facility, Zhangjiang National Laboratory, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai201204, China.

Changpeng Liu (C)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Bolong Huang (B)

Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China.

Junjie Ge (J)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.
Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian116023, China.
ORCID: 0000-0002-1561-4852

Wei Xing (W)

State Key Laboratory of Electroanalytical Chemistry, Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun130022, China.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei230026, China.

Classifications MeSH