Non-thermal structural transformation of diamond driven by x-rays.


Journal

Structural dynamics (Melville, N.Y.)
ISSN: 2329-7778
Titre abrégé: Struct Dyn
Pays: United States
ID NLM: 101660872

Informations de publication

Date de publication:
Sep 2023
Historique:
received: 18 05 2023
accepted: 10 10 2023
medline: 30 10 2023
pubmed: 30 10 2023
entrez: 30 10 2023
Statut: epublish

Résumé

Intense x-ray pulses can cause the non-thermal structural transformation of diamond. At the SACLA XFEL facility, pump x-ray pulses triggered this phase transition, and probe x-ray pulses produced diffraction patterns. Time delays were observed from 0 to 250 fs, and the x-ray dose varied from 0.9 to 8.0 eV/atom. The intensity of the (111), (220), and (311) diffraction peaks decreased with time, indicating a disordering of the crystal lattice. From a Debye-Waller analysis, the rms atomic displacements perpendicular to the (111) planes were observed to be significantly larger than those perpendicular to the (220) or (311) planes. At a long time delay of 33 ms, graphite (002) diffraction indicates that graphitization did occur above a threshold dose of 1.2 eV/atom. These experimental results are in qualitative agreement with XTANT+ simulations using a hybrid model based on density-functional tight-binding molecular dynamics.

Identifiants

pubmed: 37901681
doi: 10.1063/4.0000193
pii: 4.0000193
pmc: PMC10613085
doi:

Types de publication

Journal Article

Langues

eng

Pagination

054502

Informations de copyright

© 2023 Author(s).

Déclaration de conflit d'intérêts

The authors have no conflicts to disclose.

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Auteurs

Philip Heimann (P)

Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, USA.

Nicholas J Hartley (NJ)

SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, USA.

Ichiro Inoue (I)

RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.

Andre Antoine (A)

University of Michigan, 500 S State St, Ann Arbor, Michigan 48109, USA.

Fabien Dorchies (F)

University Bordeaux, CNRS, CEA, CELIA, UMR 5107, F-33500 Talence, France.

Roger Falcone (R)

Department of Physics, University of California, Berkeley, California 94720, USA.

Jérôme Gaudin (J)

University Bordeaux, CNRS, CEA, CELIA, UMR 5107, F-33500 Talence, France.

Hauke Höppner (H)

Helmholtz-Zentrum Dresden-Rossendorf, 01328 Dresden, Germany.

Hae Ja Lee (HJ)

Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, USA.

Paloma Martinez (P)

University Bordeaux, CNRS, CEA, CELIA, UMR 5107, F-33500 Talence, France.

Franz Tavella (F)

Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, USA.

Sven Toleikis (S)

Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany.

Jumpei Yamada (J)

RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.

Classifications MeSH