A Proof-of-Principle Design for Through-Space Transmission of Unidirectional Rotary Motion by Molecular Photogears.

density functional calculations isomerization molecular devices molecular gears photochemistry

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)

ISSN: 1521-3765

Titre abrégé: Chemistry

Pays: Germany

ID NLM: 9513783

Informations de publication

Date de publication:
31 Oct 2023

Historique:

received: 10 10 2023

pubmed: 31 10 2023

medline: 31 10 2023

entrez: 31 10 2023

Statut: aheadofprint

Résumé

The construction of molecular photogears that can achieve through-space transmission of the unidirectional double-bond rotary motion of light-driven molecular motors onto a remote single-bond axis is a formidable challenge in the field of artificial molecular machines. Here, we present a proof-of-principle design of such photogears that is based on the possibility of using stereogenic substituents to control both the relative stabilities of two helical forms of the photogear and the double-bond photoisomerization reaction that connects them. The potential of the design was verified by quantum-chemical modeling through which photogearing was found to be a favorable process compared to free-standing single-bond rotation ("slippage"). Overall, our study unveils a surprisingly simple approach to realizing unidirectional photogearing.

Identifiants

DOI: 10.1002/chem.202303191 PMID: 37906675

pubmed: 37906675

doi: 10.1002/chem.202303191

doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

Pagination

e202303191

Subventions

Organisme : Vetenskapsrådet

ID : 2019-03664

Organisme : Vetenskapsrådet

ID : 2022-06442

Organisme : Olle Engkvists Stiftelse

ID : 204-0183

Organisme : Carl Tryggers Stiftelse för Vetenskaplig Forskning

ID : CTS 20:102

Informations de copyright

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