Effect of Poly(Vinyl Pyrrolidone) on Iodine Release from Acrylate-Endcapped Urethane-Based Poly(Ethylene Glycol) Hydrogels as Antibacterial Wound Dressing.

antibacterial materials iodine mechanical strength poly(ethylene glycol) poly(vinyl pyrrolidone) swelling wound dressing

Journal

Macromolecular bioscience
ISSN: 1616-5195
Titre abrégé: Macromol Biosci
Pays: Germany
ID NLM: 101135941

Informations de publication

Date de publication:
01 Nov 2023
Historique:
revised: 11 09 2023
received: 10 05 2023
pubmed: 2 11 2023
medline: 2 11 2023
entrez: 1 11 2023
Statut: aheadofprint

Résumé

Infections are still a major cause of morbidity in burn wounds. Although silver has been used strongly in past centuries as an anti-bacterial, it can lead to allergic reactions, bacterial resistance, and delayed wound healing. Iodine-based antibacterials are becoming an interesting alternative. In this work, the effect of complexation with poly(vinyl pyrrolidone) (PVP) and poly(ethylene oxide) (PEO)-based polymers is explored by using different acrylate-endcapped urethane-based poly(ethylene glycol) (AUP) polymers, varying the molar mass (MM) of the poly(ethylene glycol) (PEG) backbone, with possible addition of PVP. The higher MM AUP outperforms the swelling potential of commercial wound dressings such as Kaltostat, Aquacel Ag, and Hydrosorb and all MM show superior mechanical properties. The addition of iodine to the polymers is compared to Iso-Betadine Tulle (IBT). Interestingly, the addition of PVP does not lead to increased iodine complexation compared to the blank AUP polymers, while all have a prolonged iodine release compared to the IBT, which leads to a burst release. The observed prolonged release also leads to larger inhibition zones during antibacterial tests. Complexing iodine in AUP polymers with or without PVP leads to antimicrobial wound dressings which may hold potential for future application to treat infected wounds.

Identifiants

pubmed: 37913549
doi: 10.1002/mabi.202300202
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2300202

Subventions

Organisme : FWO
ID : G075621N
Organisme : FWO
ID : 12Z2918N
Organisme : IOF
ID : F2018/IOF-Advanced/447

Informations de copyright

© 2023 Wiley-VCH GmbH.

Références

C. K. Murray, J. Trauma Acute Care Surg. 2008, 64, S239. https://journals.lww.com/jtrauma/Fulltext/2008/03001/Epidemiology_of_Infections_Associated_With.5.aspx
Burns, https://www.who.int/news-room/fact-sheets/detail/burns (accessed: April 2021).
D. N. Herndon, Total Burn Care: Expert Consult, 2012.
N. Brusselaers, S. Monstrey, D. Vogelaers, E. Hoste, S. Blot, Crit. Care 2010, 14, R188.
J. L. Clement, P. S. Jarrett, Met.-Based. Drugs 1994, 1, 707103.
M. Minsart, S. Van Vlierberghe, P. Dubruel, A. Mignon, Burns Trauma 2022, 10, tkac024.
S. Silver, L. T. Phung, G. Silver, J. Ind. Microbiol. Biotechnol. 2006, 33, 627.
D. Zweiker, S. Horn, A. Hoell, S. Seitz, D. Walter, M. Trop, Ann. Burns Fire Disasters 2014, 27, 197.
A.-R. C. Lee, H. Leem, J. Lee, K. C. Park, Biomaterials 2005, 26, 4670.
J.-M. Lachapelle, O. Castel, A. F. Casado, B. Leroy, G. Micali, D. Tennstedt, J. Lambert, Clin. Pract. 2013, 10, 579.
R. G. Sibbald, D. J. Leaper, D. Queen, Wounds Int. 2011, 2, s1.
R. W. Ramette, R. W. Sandford, J. Am. Chem. Soc. 1965, 87, 5001.
D. N. Payne, S. A. W. Gibson, R. Lewis, J. R. Soc. Health 1998, 118, 18.
P. L. Bigliardi, S. A. L. Alsagoff, H. Y. El-Kafrawi, J.-K. Pyon, C. T. C. Wa, M. A. Villa, Int. J. Surg. 2017, 44, 260.
W. Fleischer, K. Reimer, Dermatology 1997, 195, 3.
S. Ripa, N. Bruno, R. F. Reder, R. Casillis, R. I. Roth, in Handbook of Topical Antimicrobials: Industrial Applications in Consumer Products and Pharmaceuticals (Ed: D. S. Paulson), Marcel Dekker, New York 2003, p. 77.
G. Selvaggi, S. Monstrey, K. V. Landuyt, M. Hamdi, P. h. Blondeel, Acta Chir. Belg. 2003, 103, 241.
A. Houben, N. Pien, X.. Lu, F. Bisi, J. Van Hoorick, M. N. Boone, P. Roose, H. Van Den Bergen, D. Bontinck, T. Bowden, P. Dubruel, S. Van Vlierberghe, Macromol. Biosci. 2016, 16, 1883.
A. Mignon, D. Pezzoli, E. Prouvé, L. Lévesque, A. Arslan, N. Pien, D. Schaubroeck, J. Van Hoorick, D. Mantovani, S. Van Vlierberghe, P. Dubruel, React. Funct. Polym. 2019, 136, 95.
https://www.newpharma.be/apotheek/meda/65507/iso-betadin.-10-tule-10x10cm-geimpregneerde-verbandgazen-5.html. on 28/04/2021, Iso-Betadine 10% Tule 10×10 cm Geïmpregneerde Verbandgazen 5, (n.d.).
B. Stubbe, A. Mignon, H. Declercq, S. Van Vlierberghe, P. Dubruel, Macromol. Biosci. 2019, 19, 1900123.
E. M. Abdelrazek, A. M. Abdelghany, S. I. Badr, M. A. Morsi, J. Mater. Res. Technol. 2018, 7, 419.
S..-S.. Zhao, L. Chen, X. Zheng, L. Wang, Z. Xie, Chem. - Asian J. 2017, 12, 615.
R. Garcia-Arrona, M. Arranz, A. Bordagaray, E. Millán, J. Lab. Chem. Educ. 2017, 5, 26.
T. Coenye, Biofilm antimicrobial susceptibility testing: where are we and where could we be going?. Clinical Microbiology Reviews, 2023, e00024-23.
J. Bendoraitiene, A. Sarkinas, P. P. Danilovas, R. Rutkaite, R. Klimaviciute, A. Zemaitaitis, Cationic starch iodophores. Journal of applied polymer science 2013, 128, 4346.

Auteurs

Arn Mignon (A)

Polymer Chemistry and Biomaterials Group, Center of Macromolecular Chemistry, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281, S4-bis, 9000 Gent, Ghent, Belgium.
Smart Polymeric Biomaterials, Biomaterials and Tissue Engineering, Campus Group T, KU, Leuven, Andreas Vesaliusstraat 13, 3000, Leuven, Belgium.

Tom Gheysens (T)

Polymer Chemistry and Biomaterials Group, Center of Macromolecular Chemistry, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281, S4-bis, 9000 Gent, Ghent, Belgium.

Sander Walraet (S)

Polymer Chemistry and Biomaterials Group, Center of Macromolecular Chemistry, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281, S4-bis, 9000 Gent, Ghent, Belgium.

Pieter Tack (P)

Department of Chemistry, Ghent University, Krijgslaan 281, S12, 9000, Gent, Belgium.

Petra Rigole (P)

Laboratory of Pharmaceutical Microbiology, Ghent University, Ottergemsesteenweg 460, Gent, 9000, Belgium.

Tom Coenye (T)

Laboratory of Pharmaceutical Microbiology, Ghent University, Ottergemsesteenweg 460, Gent, 9000, Belgium.

Laszlo Vincze (L)

Department of Chemistry, Ghent University, Krijgslaan 281, S12, 9000, Gent, Belgium.

Sandra Van Vlierberghe (S)

Polymer Chemistry and Biomaterials Group, Center of Macromolecular Chemistry, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281, S4-bis, 9000 Gent, Ghent, Belgium.

Peter Dubruel (P)

Polymer Chemistry and Biomaterials Group, Center of Macromolecular Chemistry, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281, S4-bis, 9000 Gent, Ghent, Belgium.

Classifications MeSH