Reactive high-spin iron(IV)-oxo sites through dioxygen activation in a metal-organic framework.

Journal

Science (New York, N.Y.)
ISSN: 1095-9203
Titre abrégé: Science
Pays: United States
ID NLM: 0404511

Informations de publication

Date de publication:
03 Nov 2023
Historique:
medline: 2 11 2023
pubmed: 2 11 2023
entrez: 2 11 2023
Statut: ppublish

Résumé

In nature, nonheme iron enzymes use dioxygen to generate high-spin iron(IV)=O species for a variety of oxygenation reactions. Although synthetic chemists have long sought to mimic this reactivity, the enzyme-like activation of O

Identifiants

DOI: 10.1126/science.add7417 PMID: 37917685
pubmed: 37917685
doi: 10.1126/science.add7417
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

547-553

Auteurs

Kaipeng Hou (K)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
ORCID: 0000-0002-4816-7067

Jonas Börgel (J)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
ORCID: 0000-0001-5301-8579

Henry Z H Jiang (HZH)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0002-8086-3601

Daniel J SantaLucia (DJ)

Max Planck Institute for Chemical Energy Conversion, D-45470 Mülheim an der Ruhr, Germany.
Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim an der Ruhr, Germany.
ORCID: 0000-0002-4201-6612

Hyunchul Kwon (H)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0001-6558-7744

Hao Zhuang (H)

Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720, USA.
Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA.

Khetpakorn Chakarawet (K)

Department of Chemistry, University of California, Davis, CA 95616, USA.
ORCID: 0000-0001-5905-3578

Rachel C Rohde (RC)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0003-1621-2203

Jordan W Taylor (JW)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0003-1675-9452

Chaochao Dun (C)

The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
ORCID: 0000-0002-3215-6478

Maria V Paley (MV)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
ORCID: 0000-0001-9142-4404

Ari B Turkiewicz (AB)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0001-5729-0289

Jesse G Park (JG)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0003-3947-9170

Haiyan Mao (H)

Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0003-0591-1236

Ziting Zhu (Z)

Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0002-4173-0347

E Ercan Alp (EE)

Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA.
ORCID: 0000-0002-4803-8863

Jiyong Zhao (J)

Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA.
ORCID: 0000-0002-0777-3626

Michael Y Hu (MY)

Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA.
ORCID: 0000-0002-3718-7169

Barbara Lavina (B)

Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA.
Center for Advanced Radiation Sources, The University of Chicago, Chicago, IL 60637, USA.
ORCID: 0000-0002-8556-7916

Sergey Peredkov (S)

Max Planck Institute for Chemical Energy Conversion, D-45470 Mülheim an der Ruhr, Germany.
ORCID: 0000-0002-5816-9015

Xudong Lv (X)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0002-5601-3789

Julia Oktawiec (J)

Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.
ORCID: 0000-0002-2895-3327

Katie R Meihaus (KR)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.

Dimitrios A Pantazis (DA)

Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim an der Ruhr, Germany.
ORCID: 0000-0002-2146-9065

Marco Vandone (M)

Department of Chemistry, University of Milan, 20133 Milan, Italy.
ORCID: 0000-0003-2835-4663

Valentina Colombo (V)

Department of Chemistry, University of Milan, 20133 Milan, Italy.
Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM), UdR Milano, Via Golgi 19, 20133 Milano, Italy.
ORCID: 0000-0003-0263-4456

Eckhard Bill (E)

Max Planck Institute for Chemical Energy Conversion, D-45470 Mülheim an der Ruhr, Germany.

Jeffrey J Urban (JJ)

Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
ORCID: 0000-0003-4909-2869

R David Britt (RD)

Department of Chemistry, University of California, Davis, CA 95616, USA.
Miller Institute for Basic Research in Science, University of California, Berkeley CA 94720, USA.
ORCID: 0000-0003-0889-8436

Fernande Grandjean (F)

Department of Chemistry, Missouri University of Science and Technology, University of Missouri, Rolla, MO 65409, USA.
ORCID: 0000-0001-5456-3915

Gary J Long (GJ)

Department of Chemistry, Missouri University of Science and Technology, University of Missouri, Rolla, MO 65409, USA.
ORCID: 0000-0002-6573-5927

Serena DeBeer (S)

Max Planck Institute for Chemical Energy Conversion, D-45470 Mülheim an der Ruhr, Germany.
ORCID: 0000-0002-5196-3400

Frank Neese (F)

Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim an der Ruhr, Germany.
ORCID: 0000-0003-4691-0547

Jeffrey A Reimer (JA)

Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0002-4191-3725

Jeffrey R Long (JR)

Department of Chemistry, University of California, Berkeley, CA 94720, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720, USA.
ORCID: 0000-0002-5324-1321

Classifications MeSH