An emissive charge-transfer excited-state at the well-defined hetero-nanostructure interface of an organic conjugated molecule and two-dimensional inorganic nanosheet.


Journal

Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951

Informations de publication

Date de publication:
01 Nov 2023
Historique:
received: 13 07 2023
accepted: 03 10 2023
medline: 3 11 2023
pubmed: 3 11 2023
entrez: 3 11 2023
Statut: epublish

Résumé

Precise engineering of excited-state interactions between an organic conjugated molecule and a two-dimensional semiconducting inorganic nanosheet, specifically the manipulation of charge-transfer excited (CTE) states, still remains a challenge for state-of-the-art photochemistry. Herein, we report a long-lived, highly emissive CTE state at structurally well-defined hetero-nanostructure interfaces of photoactive pyrene and two-dimensional MoS

Identifiants

pubmed: 37920360
doi: 10.1039/d3sc03604a
pii: d3sc03604a
pmc: PMC10619621
doi:

Types de publication

Journal Article

Langues

eng

Pagination

11914-11923

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Tomokazu Umeyama (T)

Department of Applied Chemistry, Graduate School of Engineering, University of Hyogo Himeji Hyogo 671-2280 Japan umeyama@eng.u-hyogo.ac.jp.

Daizu Mizutani (D)

Department of Molecular Engineering, Graduate School of Engineering, Kyoto University Kyoto 615-8510 Japan higashi@moleng.kyoto-u.ac.jp imahori@scl.kyoto-u.ac.jp.

Yuki Ikeda (Y)

Department of Molecular Engineering, Graduate School of Engineering, Kyoto University Kyoto 615-8510 Japan higashi@moleng.kyoto-u.ac.jp imahori@scl.kyoto-u.ac.jp.

W Ryan Osterloh (WR)

Department of Molecular Engineering, Graduate School of Engineering, Kyoto University Kyoto 615-8510 Japan higashi@moleng.kyoto-u.ac.jp imahori@scl.kyoto-u.ac.jp.

Futa Yamamoto (F)

Department of Applied Chemistry, Graduate School of Engineering, University of Hyogo Himeji Hyogo 671-2280 Japan umeyama@eng.u-hyogo.ac.jp.

Kosaku Kato (K)

Graduate School of Natural Science and Technology, Okayama University Okayama 700-8530 Japan yamakata@okayama-u.ac.jp.

Akira Yamakata (A)

Graduate School of Natural Science and Technology, Okayama University Okayama 700-8530 Japan yamakata@okayama-u.ac.jp.

Masahiro Higashi (M)

Department of Molecular Engineering, Graduate School of Engineering, Kyoto University Kyoto 615-8510 Japan higashi@moleng.kyoto-u.ac.jp imahori@scl.kyoto-u.ac.jp.

Takumi Urakami (T)

Department of Molecular Engineering, Graduate School of Engineering, Kyoto University Kyoto 615-8510 Japan higashi@moleng.kyoto-u.ac.jp imahori@scl.kyoto-u.ac.jp.

Hirofumi Sato (H)

Department of Molecular Engineering, Graduate School of Engineering, Kyoto University Kyoto 615-8510 Japan higashi@moleng.kyoto-u.ac.jp imahori@scl.kyoto-u.ac.jp.

Hiroshi Imahori (H)

Department of Molecular Engineering, Graduate School of Engineering, Kyoto University Kyoto 615-8510 Japan higashi@moleng.kyoto-u.ac.jp imahori@scl.kyoto-u.ac.jp.
Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University Kyoto 606-8501 Japan.
Institute for Liberal Arts and Sciences (ILAS), Kyoto University Kyoto 606-8501 Japan.

Classifications MeSH