Diammonium spacer-induced stable zigzag type 2D Dion-Jacobson lead/tin-based perovskite solar cells.

Hybrid halide two dimensional (2D) perovskites have attracted considerable attention because they exhibit an improvement in perovskite solar cells compared with their 3D analogs. However, their bulky organic space group, leading to higher bandgaps and exciton binding energy, limits the charge transport in solar cells. Herein, the 3-(aminomethyl)pyridinium (3API