Direct Electrochemical Synthesis of Acetamide from CO

The electrochemical conversion of carbon dioxide into value-added compounds not only paves the way toward a sustainable society but also unlocks the potential for electrocatalytic synthesis of amides through the introduction of N atoms. However, it also poses one of the greatest challenges in catalysis: achieving simultaneous completion of C-C coupling and C-N coupling. Here, we have meticulously investigated the catalytic prowess of Cu-based single-atom alloys in facilitating the electrochemical synthesis of acetamide from CO