Recent Advances in Monocomponent Visible Light Photoinitiating Systems Based on Sulfonium Salts.
LED
monocomponent
photoacid generator
photoinitiator
photopolymerization
sulfonium
visible light
Journal
Polymers
ISSN: 2073-4360
Titre abrégé: Polymers (Basel)
Pays: Switzerland
ID NLM: 101545357
Informations de publication
Date de publication:
24 Oct 2023
24 Oct 2023
Historique:
received:
21
09
2023
revised:
15
10
2023
accepted:
18
10
2023
medline:
14
11
2023
pubmed:
14
11
2023
entrez:
14
11
2023
Statut:
epublish
Résumé
During the last decades, multicomponent photoinitiating systems have been the focus of intense research efforts, especially for the design of visible light photoinitiating systems. Although highly reactive three-component and even four-component photoinitiating systems have been designed, the complexity to elaborate such mixtures has incited researchers to design monocomponent Type II photoinitiators. Using this approach, the photosensitizer and the radical/cation generator can be combined within a unique molecule, greatly simplifying the elaboration of the photocurable resins. In this field, sulfonium salts are remarkable photoinitiators but these structures lack absorption in the visible range. Over the years, various structural modifications have been carried out in order to redshift their absorptions in the visible region. In this work, an overview of the different sulfonium salts activable under visible light and reported to date is proposed.
Identifiants
pubmed: 37959882
pii: polym15214202
doi: 10.3390/polym15214202
pmc: PMC10649563
pii:
doi:
Types de publication
Journal Article
Review
Langues
eng
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