Noncovalent interaction guided selectivity of haloaromatic isomers in a flexible porous coordination polymer.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
08 Nov 2023
08 Nov 2023
Historique:
received:
16
06
2023
accepted:
04
10
2023
medline:
16
11
2023
pubmed:
16
11
2023
entrez:
16
11
2023
Statut:
epublish
Résumé
Porous, supramolecular structures exhibit preferential encapsulation of guest molecules, primarily by means of differences in the order of (noncovalent) interactions. The encapsulation preferences can be for geometry (dimension and shape) and the chemical nature of the guest. While geometry-based sorting is relatively straightforward using advanced porous materials, designing a "chemical nature" specific host is not. To introduce "chemical specificity", the host must retain an accessible and complementary recognition site. In the case of a supramolecular, porous coordination polymer (PCP) [Zn(
Identifiants
pubmed: 37969590
doi: 10.1039/d3sc03079b
pii: d3sc03079b
pmc: PMC10631220
doi:
Types de publication
Journal Article
Langues
eng
Pagination
12321-12330Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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