Biogeochemical cycling in paddy soils controls antimony transformation: Roles of iron (oxyhydr)oxides, organic matter and sulfate.

In paddy fields, periodic flooding and drainage phases can significantly affect the availability of antimony (Sb), but the underlying mechanisms remain unclear. In this study, Sb-contaminated paddy soil was incubated under anaerobic (40 day) and subsequently aerobic (40-55 day) conditions. The Sb fractions was investigated and a kinetic model was established to quantitatively evaluate the main processes controlling Sb transformation. Under anaerobic conditions, the reductive dissolution of iron (Fe) (oxyhydr)oxides, the release of soil colloids, and dissolved organic carbon (DOC) could facilitate the release of Sb(V), while newly released Sb(V) were synchronously reduced to Sb(III) that could be incorporated into the solid phase (34.1%, 40 day) or precipitated as Sb

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Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.