Dormancy and double-activation strategy for construction of high-performance mixed-matrix membranes.

CO2 Capture Mixed Matrix Membranes Quasi-Semi-Continuous Mass Transfer Channels Ultrahigh ZIF-8 Loadings

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
20 Nov 2023
Historique:
received: 09 10 2023
pubmed: 20 11 2023
medline: 20 11 2023
entrez: 20 11 2023
Statut: aheadofprint

Résumé

Mixed-matrix membranes (MMMs) have the potential for energy-efficient gas separation by matching the superior mass transfer and anti-plasticization properties of the fillers with processability and scaling up features of the polymers. However, construction of high-performance MMMs has been prohibited due to low filler-loading and the existence of interfacial defects. Here, high MOF-loaded, i.e., 55 wt %, MMMs are developed by a 'dormancy and double-activation' (DDA) strategy. High MOF precursor concentration suppresses crystallization in the membrane casting solution, realizing molecular level mixing of all components. Then, the polymeric matrix was formed with uniform encapsulation of MOF nutrients. Subsequently, double-activation was employed to induce MOF crystallization: the alkali promotes MOFs nucleation to harvest small porous nanocrystals while excessive ligands activate the metal ions to enhance the MOFs conversion. As such, quasi-semi-continuous mass transfer channels can be formed in the MMMs by the connected MOFs nanocrystals to boost the gas permeability. The optimized MMM shows significantly ameliorated CO

Identifiants

pubmed: 37983657
doi: 10.1002/anie.202315167
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202315167

Subventions

Organisme : National Natural Science Foundation of China
ID : 22125801
Organisme : National Natural Science Foundation of China
ID : 21975005
Organisme : Australian Research Council
ID : DP180103861
Organisme : Australian Research Council
ID : IH170100009

Informations de copyright

© 2023 Wiley-VCH GmbH.

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Auteurs

Shuo Li (S)

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemical Engineering, Beijing University of Technology, Beijing, 100124, China.

Wei-Yao Han (WY)

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemical Engineering, Beijing University of Technology, Beijing, 100124, China.

Zhao-Xu Wang (ZX)

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemical Engineering, Beijing University of Technology, Beijing, 100124, China.

Yu-Jie Sun (YJ)

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemical Engineering, Beijing University of Technology, Beijing, 100124, China.

Zilong Zheng (Z)

Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China.

Ming-Jie Yin (MJ)

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemical Engineering, Beijing University of Technology, Beijing, 100124, China.

Shaomin Liu (S)

WA School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Bentley, WA 6102, Australia.

Quan-Fu An (QF)

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemical Engineering, Beijing University of Technology, Beijing, 100124, China.

Classifications MeSH