Conversion of N-Acetylglucosamine to 3-Acetamido-5-Acetylfuran over Al-Exchanged Montmorillonite.
biomass
clays
nitrogen-containing compounds
recyclable solid catalyst
shell biorefinery
Journal
ChemistryOpen
ISSN: 2191-1363
Titre abrégé: ChemistryOpen
Pays: Germany
ID NLM: 101594811
Informations de publication
Date de publication:
Dec 2023
Dec 2023
Historique:
revised:
09
10
2023
received:
30
07
2023
medline:
21
11
2023
pubmed:
21
11
2023
entrez:
21
11
2023
Statut:
ppublish
Résumé
3-Acetamido-5-acetylfuran (3A5AF) is a potential platform compound for the production of nitrogen-containing pharmaceuticals and chemicals. 3A5AF can be obtained by dehydration of chitin or its monomer, N-acetylglucosamine (NAG). Here, we examined the use of solid catalysts for the dehydration of NAG to 3A5AF to achieve a more economical process that uses a recyclable catalyst. NAG was dehydrated using various solid catalysts in the presence of NaCl and N,N-dimethyl acetamide as solvent at 433 K. The yield of 3A5AF with the solid catalysts decreased in the following order: Al-exchanged montmorillonite>H-ZSM-5 (SiO
Identifiants
pubmed: 37988701
doi: 10.1002/open.202300148
pmc: PMC10695736
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202300148Subventions
Organisme : Japan Society for the Promotion of Science KAKENHI
ID : JP22H00578
Organisme : Ebara Hatakeyama Memorial Foundation
Informations de copyright
© 2023 The Authors. ChemistryOpen published by Wiley-VCH GmbH.
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