Sesquiterpene Backbones Generated by Sesquiterpene Cyclases: Formation of
Journal
Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393
Informations de publication
Date de publication:
08 Dec 2023
08 Dec 2023
Historique:
pubmed:
27
11
2023
medline:
27
11
2023
entrez:
27
11
2023
Statut:
ppublish
Résumé
New sesquiterpene backbones are accessible after incubation of caryolan-synthase (GcoA) and presilphiperfolan-8-β-ol synthase (BcBOT2) with a non-natural farnesyldiphosphate in which the central olefinic double bond is isomerized toward the methyl group. Two newly formed sesquiterpenoids are reported, a constitutional isomer of caryolan-1-ol (
Identifiants
pubmed: 38011332
doi: 10.1021/acs.orglett.3c03383
pmc: PMC10714441
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
8575-8579Références
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