Biocatalytic reduction of alkenes in micro-aqueous organic solvent catalysed by an immobilised ene reductase.


Journal

Catalysis science & technology
ISSN: 2044-4753
Titre abrégé: Catal Sci Technol
Pays: England
ID NLM: 101636664

Informations de publication

Date de publication:
02 Oct 2023
Historique:
received: 19 04 2023
accepted: 22 05 2023
medline: 28 11 2023
pubmed: 28 11 2023
entrez: 28 11 2023
Statut: epublish

Résumé

Biocatalytic asymmetric reduction of alkenes in organic solvent is attractive for enantiopurity and product isolation, yet remains under developed. Herein we demonstrate the robustness of an ene reductase immobilised on Celite for the reduction of activated alkenes in micro-aqueous organic solvent. Full conversion was obtained in methyl

Identifiants

pubmed: 38013840
doi: 10.1039/d3cy00541k
pii: d3cy00541k
pmc: PMC10544049
doi:

Types de publication

Journal Article

Langues

eng

Pagination

5530-5535

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

Références

Angew Chem Int Ed Engl. 2014 Mar 17;53(12):3070-95
pubmed: 24520044
Adv Synth Catal. 2018 Jul 16;360(14):2742-2751
pubmed: 30147639
Angew Chem Int Ed Engl. 2018 Jun 11;57(24):7240-7244
pubmed: 29689601
Eur J Biochem. 1991 Aug 1;199(3):609-14
pubmed: 1868847
Green Chem. 2021 Mar 26;23(9):3191-3206
pubmed: 34093084
Enzyme Microb Technol. 2018 Feb;109:66-73
pubmed: 29224628
Chem Soc Rev. 2009 Feb;38(2):453-68
pubmed: 19169460
Int J Mol Sci. 2022 Mar 11;23(6):
pubmed: 35328465
Protein Eng Des Sel. 2008 Nov;21(11):673-80
pubmed: 18799474
Adv Synth Catal. 2009 Nov;351(17):2976-2990
pubmed: 20396613
Chem Commun (Camb). 2021 Nov 2;57(87):11416-11428
pubmed: 34636371
Org Lett. 2011 May 20;13(10):2540-3
pubmed: 21510626
Biotechnol Lett. 2014 Jun;36(6):1329-33
pubmed: 24563324
J Biol Chem. 1998 Dec 4;273(49):32763-70
pubmed: 9830020
Chem Soc Rev. 2013 Aug 7;42(15):6211-2
pubmed: 23807229
RSC Chem Biol. 2021 Jun 1;2(4):958-989
pubmed: 34458820
J Am Chem Soc. 2023 Jan 18;145(2):787-793
pubmed: 36608280
J Biotechnol. 2020 Nov 10;323:246-253
pubmed: 32891641
Front Microbiol. 2018 Oct 12;9:2410
pubmed: 30369915
ACS Catal. 2019 May 15;8(4):3532-3549
pubmed: 31157123
ChemSusChem. 2019 Jul 5;12(13):2859-2881
pubmed: 30938093
Chembiochem. 2010 Jan 25;11(2):197-207
pubmed: 19943268
Biochem Biophys Res Commun. 2010 Mar 12;393(3):426-31
pubmed: 20138824
Adv Synth Catal. 2020 Apr 27;362(9):1858-1867
pubmed: 32421034
Dalton Trans. 2010 Sep 28;39(36):8472-6
pubmed: 20461254
Chembiochem. 2007 Dec 17;8(18):2295-301
pubmed: 17990264
J Am Chem Soc. 2016 Jan 27;138(3):1033-9
pubmed: 26727612
Chembiochem. 2022 Jan 5;23(1):e202100445
pubmed: 34586700
Curr Opin Chem Biol. 2018 Apr;43:97-105
pubmed: 29275291

Auteurs

Rocio Villa (R)

Biocatalysis section, Department of Biotechnology, Delft University of Biotechnology van der Maasweg 9 2629 HZ Delft The Netherlands c.e.paul@tudelft.nl.

Claudia Ferrer-Carbonell (C)

Biocatalysis section, Department of Biotechnology, Delft University of Biotechnology van der Maasweg 9 2629 HZ Delft The Netherlands c.e.paul@tudelft.nl.

Caroline E Paul (CE)

Biocatalysis section, Department of Biotechnology, Delft University of Biotechnology van der Maasweg 9 2629 HZ Delft The Netherlands c.e.paul@tudelft.nl.

Classifications MeSH