Flexibility in zeolites: origin, limits, and evaluation.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
15 Nov 2023
15 Nov 2023
Historique:
received:
29
07
2023
accepted:
12
10
2023
medline:
29
11
2023
pubmed:
29
11
2023
entrez:
29
11
2023
Statut:
epublish
Résumé
Numerous pieces of evidence in the literature suggest that zeolitic materials exhibit significant intrinsic flexibility as a consequence of the spring-like behavior of Si-O and Al-O bonds and the distortion ability of Si-O-Si and Al-O-Si angles. Understanding the origin of flexibility and how it may be tuned to afford high adsorption selectivity in zeolites is a big challenge. Zeolite flexibility may be triggered by changes in temperature, pressure, or chemical composition of the framework and extra-framework compounds, as well as by the presence of guest molecules. Therefore, zeolite flexibility can be classified into three categories: (i) temperature and pressure-induced flexibility; (ii) guest-induced flexibility; and (iii) compositionally-induced flexibility. An outlook on zeolite flexibility and the challenges met during the precise experimental evaluations of zeolites will be discussed. Overcoming these challenges will provide an important tool for designing novel selective adsorbents.
Identifiants
pubmed: 38020361
doi: 10.1039/d3sc03934j
pii: d3sc03934j
pmc: PMC10646982
doi:
Types de publication
Journal Article
Review
Langues
eng
Pagination
12430-12446Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
There are no conflicts to declare.
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