Understanding the Poly (Triazine Imide) Crystals Formation Process: The Conversion from Heptazine to Triazine.
heptazine
overall water splitting
photocatalysis
structure evolution
triazine
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
29 Nov 2023
29 Nov 2023
Historique:
received:
14
09
2023
pubmed:
30
11
2023
medline:
30
11
2023
entrez:
30
11
2023
Statut:
aheadofprint
Résumé
Poly (triazine imide) (PTI) generally obtained via ionothermal synthesis features extended π-conjugation and enhanced crystallinity. However, in-depth investigation of the polycondensation process for PTI is an onerous task due to multiple influencing factors and limited characterization techniques. Herein, to simplify the polymerization route and exclude non-essential factors, PTI was prepared by calcining only melamine and LiCl. This study aims to identify the pivotal role of LiCl in PTI formation, which can convert heptazine-based intermediates into more stable triazine-based PTI framework. Based on this discovery, we demonstrate the transformation process of the prepared samples from amorphous Bulk g-C
Identifiants
pubmed: 38031382
doi: 10.1002/chem.202302982
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202302982Subventions
Organisme : Natural Science Foundation of Anhui Province
ID : 2308085MB60
Informations de copyright
© 2023 Wiley-VCH GmbH.
Références
L. Lin, C. Wang, W. Ren, H. Ou, Y. Zhang, X. Wang, Chem. Sci. 2017, 8, 5506-5511;
S. Wang, D. Li, C. Sun, S. Yang, Y. Guan, H. He, Appl. Catal. B. 2014, 144, 885-892.
J. Wang, S. Wang, Coord. Chem. Rev. 2022, 453, 214338;
X. Wang, K. Maeda, A. Thomas, K. Takanabe, G. Xin, J. M. Carlsson, K. Domen, M. Antonietti, Nat. Mater. 2009, 8, 76-80.
Y. Zhao, J. Zhang, L. T. Qu, ChemNanoMat 2015, 1, 298-318.
J. Mo, N. Wang, S. Zhang, X. Chen, J. Fu, P. Chen, Z. Liang, Q. Su, X. Li, Res. Chem. Intermed. 2022, 48, 3835-3849;
E. Kroke, M. Schwarz, E. Horath-Bordon, P. Kroll, B. Noll, A. D. Norman, New J. Chem. 2002, 26, 508-512.
M. J. Bojdys, J. Müller, M. Antonietti, A. Thomas, Chem. Eur. J. 2008, 14, 8177-8182.
J. Wu, Z. Liu, X. Lin, E. Jiang, S. Zhang, P. Huo, Y. Yan, P. Zhou, Y. Yan, Nat. Commun. 2022, 13, 6999.
G. Algara-Siller, N. Severin, S. Y. Chong, T. Björkman, R. G. Palgrave, A. Laybourn, M. Antonietti, Y. Z. Khimyak, A. V. Krasheninnikov, J. P. Rabe, U. Kaiser, A. I. Cooper, A. Thomas, M. J. Bojdys, Angew. Chem. Int. Ed. 2014, 53, 7450-7455;
E. Wirnhier, M. Döblinger, D. Gunzelmann, J. Senker, B. V. Lotsch, W. Schnick, Chem. Eur. J. 2011, 11, 3213-3221.
L. Lin, Z. Lin, J. Zhang, X. Cai, W. Lin, Z. Yu, X. Wang, Nat. Catal. 2020, 3, 649-655.
M. Liu, C. Wei, H. Zhuzhang, J. Zhou, Z. Pan, W. Lin, Z. Yu, G. Zhang, X. Wang, Angew. Chem. Int. Ed. 2021, 61, e202113389;
J. Zhang, X. Liang, C. Zhang, L. Lin, W. Xing, Z. Yu, G. Zhang, X. Wang, Angew. Chem. Int. Ed. 2022, 61, e202210849.
G. Li, Z. Xie, S. Chai, X. Chen, X. Wang, Appl. Catal. B. 2021, 283, 119637;
W. F. Kong, L. Huang, X. Quan, G. L. Puma, Appl. Catal. B. 2022, 307, 122240.
L. Lin, W. Ren, C. Wang, A. M. Asiri, J. Zhang, X. Wang, Appl. Catal. B. 2018, 231, 234-241.
H. Sun, Y. Shi, W. Shi, F. Guo, Appl. Surf. Sci. 2022, 593, 153281;
S. M. Ghoreishian, G. S. R. Raju, K. Ranjith, H. Lee, C. Kwak, B. Park, S. Z. Nikoo, Y. Han, Y. Huh, Appl. Surf. Sci. 2020, 511, 145469.
Z. Chen, E. Vorobyeva, S. Mitchell, E. Fako, N. López, S. M. Collins, R. K. Leary, P. A. Midgley, R. Hauert, J. Pérez-Ramírez, Natl. Sci. Rev. 2018, 5, 642-652;
L. Du, B. Gao, S. Xu, Q. Xu, Nat. Commun. 2023, 1, 2278.
G. Zhang, Z. Lan, X. Wang, Chem. Sci. 2017, 8, 5261-5274.
W. Sun, H. Cheng, J. Zhang, X. Fang, W. Chen, J. Zhu, Y. Zheng, Chem. Eng. J. 2023, 462, 142337.
M. Antonpoulou, P. Bika, I. Papailias, S. Zervou, A. Vrettou, I. Efthimiou, G. Mitrikas, N. Ioannidis, C. Trapalis, P. Dallas, D. Vlastos, A. Hiskia, Sci. Total Environ. 2023, 892, 164218.