Copper Phosphinate Complexes as Molecular Precursors for Ethanol Dehydrogenation Catalysts.
Journal
Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543
Informations de publication
Date de publication:
11 Dec 2023
11 Dec 2023
Historique:
medline:
30
11
2023
pubmed:
30
11
2023
entrez:
30
11
2023
Statut:
ppublish
Résumé
Nowadays, the production of acetaldehyde heavily relies on the petroleum industry. Developing new catalysts for the ethanol dehydrogenation process that could sustainably substitute current acetaldehyde production methods is highly desired. Among the ethanol dehydrogenation catalysts, copper-based materials have been intensively studied. Unfortunately, the Cu-based catalysts suffer from sintering and coking, which lead to rapid deactivation with time-on-stream. Phosphorus doping has been demonstrated to diminish coking in methanol dehydrogenation, fluid catalytic cracking, and ethanol-to-olefin reactions. This work reports a pioneering application of the well-characterized copper phosphinate complexes as molecular precursors for copper-based ethanol dehydrogenation catalysts enriched with phosphate groups (
Identifiants
pubmed: 38032353
doi: 10.1021/acs.inorgchem.3c01678
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
19871-19886Références
Acta Crystallogr C. 2003 Dec;59(Pt 12):m523-5
pubmed: 14671348
J Am Chem Soc. 2022 Jul 13;144(27):12261-12271
pubmed: 35770916
Angew Chem Int Ed Engl. 2009;48(48):9034-7
pubmed: 19834923
Inorg Chem. 2015 Dec 21;54(24):11751-66
pubmed: 26615961
Inorg Chem. 2011 Feb 21;50(4):1420-8
pubmed: 21250684
Angew Chem Int Ed Engl. 2000 Jul 3;39(13):2320-2322
pubmed: 10941077
Dalton Trans. 2013 Jun 21;42(23):8192-6
pubmed: 23660753
Inorg Chem. 1997 May 21;36(11):2465-2468
pubmed: 11669889
Inorg Chem. 2008 Oct 20;47(20):9553-60
pubmed: 18781736
Chem Commun (Camb). 2013 Feb 14;49(13):1315-7
pubmed: 23303192
Dalton Trans. 2007 Jun 21;(23):2405-10
pubmed: 17844662
Nat Methods. 2012 Jul;9(7):671-5
pubmed: 22930834
Dalton Trans. 2019 May 15;48(19):6539-6545
pubmed: 31011721
J Am Chem Soc. 2002 Jul 17;124(28):8380-8
pubmed: 12105919
Chem Asian J. 2019 Aug 1;14(15):2685-2693
pubmed: 31152680
Chem Soc Rev. 2015 Oct 21;44(20):7406-28
pubmed: 26051875
Methods Enzymol. 1997;276:307-26
pubmed: 27754618
Chem Commun (Camb). 2008 Dec 21;(47):6381-3
pubmed: 19048162
Inorg Chem. 2005 May 30;44(11):4008-16
pubmed: 15907129
Inorg Chem. 2008 Feb 4;47(3):1067-73
pubmed: 18183972
J Mater Chem B. 2021 Apr 28;9(16):3523-3532
pubmed: 33909739
Acta Crystallogr A Found Adv. 2015 Jan;71(Pt 1):3-8
pubmed: 25537383
Chemistry. 2004 Jan 5;10(1):190-207
pubmed: 14695564
ChemSusChem. 2016 Jun 22;9(12):1462-72
pubmed: 27198471
Inorg Chem. 1998 Oct 19;37(21):5575-5582
pubmed: 11670704
ACS Sustain Chem Eng. 2023 Jul 20;11(30):10980-10992
pubmed: 37538293
Dalton Trans. 2017 Aug 8;46(31):10484-10497
pubmed: 28758669
Acta Crystallogr C Struct Chem. 2015 Jan;71(Pt 1):3-8
pubmed: 25567568
J Am Chem Soc. 2013 Sep 25;135(38):14032-5
pubmed: 24041129
Inorg Chem. 2017 Sep 5;56(17):10155-10161
pubmed: 28806872
Dalton Trans. 2017 May 23;46(20):6756-6761
pubmed: 28489100
Nanomaterials (Basel). 2022 Aug 02;12(15):
pubmed: 35957081
Angew Chem Int Ed Engl. 2018 Jun 25;57(26):7697-7702
pubmed: 29768706
Dalton Trans. 2015 Feb 28;44(8):3720-3
pubmed: 25622712
Nanomaterials (Basel). 2018 Jul 14;8(7):
pubmed: 30011892
RSC Adv. 2018 Jan 25;8(9):4595-4603
pubmed: 35539532
Inorg Chem. 2012 May 21;51(10):5605-16
pubmed: 22574912
Dalton Trans. 2009 Sep 14;(34):6712-4
pubmed: 19690679
J Am Chem Soc. 2007 Oct 17;129(41):12342-3
pubmed: 17880213