Phase Transitions, Dielectric Response, and Nonlinear Optical Properties of Aziridinium Lead Halide Perovskites.


Journal

Chemistry of materials : a publication of the American Chemical Society
ISSN: 0897-4756
Titre abrégé: Chem Mater
Pays: United States
ID NLM: 9884133

Informations de publication

Date de publication:
28 Nov 2023
Historique:
received: 29 08 2023
revised: 31 10 2023
accepted: 31 10 2023
medline: 4 12 2023
pubmed: 4 12 2023
entrez: 4 12 2023
Statut: epublish

Résumé

Hybrid organic-inorganic lead halide perovskites are promising candidates for next-generation solar cells, light-emitting diodes, photodetectors, and lasers. The structural, dynamic, and phase-transition properties play a key role in the performance of these materials. In this work, we use a multitechnique experimental (thermal, X-ray diffraction, Raman scattering, dielectric, nonlinear optical) and theoretical (machine-learning force field) approach to map the phase diagrams and obtain information on molecular dynamics and mechanism of the structural phase transitions in novel 3D AZRPbX

Identifiants

pubmed: 38047186
doi: 10.1021/acs.chemmater.3c02200
pmc: PMC10687860
doi:

Types de publication

Journal Article

Langues

eng

Pagination

9725-9738

Informations de copyright

© 2023 The Authors. Published by American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

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Auteurs

Mirosław Mączka (M)

Institute of Low Temperature and Structure Research, Polish Academy of Sciences, ul. Okólna 2, 50-422 Wrocław, Poland.

Maciej Ptak (M)

Institute of Low Temperature and Structure Research, Polish Academy of Sciences, ul. Okólna 2, 50-422 Wrocław, Poland.

Anna Gągor (A)

Institute of Low Temperature and Structure Research, Polish Academy of Sciences, ul. Okólna 2, 50-422 Wrocław, Poland.

Jan K Zaręba (JK)

Institute of Advanced Materials, Faculty of Chemistry, Wrocław University of Science and Technology, 50-370 Wrocław, Poland.

Xia Liang (X)

Department of Materials, Imperial College London, South Kensington Campus, London SW7 2AZ, U.K.

Sergejus Balčiu Nas (S)

Faculty of Physics, Vilnius University, LT-10257 Vilnius, Lithuania.

Oleksandr A Semenikhin (OA)

Department of Chemistry, Taras Shevchenko National University of Kyiv, 64 Volodymyrska St., Kyiv 01601, Ukraine.

Olesia I Kucheriv (OI)

Department of Chemistry, Taras Shevchenko National University of Kyiv, 64 Volodymyrska St., Kyiv 01601, Ukraine.

Il'ya A Gural'skiy (IA)

Department of Chemistry, Taras Shevchenko National University of Kyiv, 64 Volodymyrska St., Kyiv 01601, Ukraine.

Sergiu Shova (S)

Department of Inorganic Polymers, Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41-A, Iasi 700487, Romania.

Aron Walsh (A)

Department of Materials, Imperial College London, South Kensington Campus, London SW7 2AZ, U.K.
Department of Physics, Ewha Womans University, Seoul 03760, Korea.

Ju Ras Banys (JR)

Faculty of Physics, Vilnius University, LT-10257 Vilnius, Lithuania.

Mantas Šimėnas (M)

Faculty of Physics, Vilnius University, LT-10257 Vilnius, Lithuania.

Classifications MeSH