New Frontiers in Alkali-Metal Nickelates.
Alkali-Metals
Catalysis
Cross-Coupling
Heterobimetallics
Nickel
Journal
Chimia
ISSN: 0009-4293
Titre abrégé: Chimia (Aarau)
Pays: Switzerland
ID NLM: 0373152
Informations de publication
Date de publication:
26 Apr 2023
26 Apr 2023
Historique:
received:
22
01
2023
accepted:
27
02
2023
medline:
4
12
2023
pubmed:
4
12
2023
entrez:
4
12
2023
Statut:
epublish
Résumé
Recent advances in heterobimetallic chemistry have revealed the potential for mixed-metal systems to facilitate reactions that are unattainable with their single-metal components. This perspective explores the pairing of nickel(0) complexes with organo-alkali-metal reagents, which yield highly reactive alkali-metal nickelates. These previously underexplored systems have re-emerged as a promising area of research, with recent studies uncovering their unique bonding and structural motifs. Furthermore, the discovery of nickelates as potential intermediates in cross-coupling reactions has provided the foundation for the development and mechanistic understanding of stoichiometric and catalytic transformations.
Identifiants
pubmed: 38047804
doi: 10.2533/chimia.2023.242
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
242-245Subventions
Organisme : Swiss National Science Foundation
ID : 188573
Pays : Switzerland
Informations de copyright
Copyright 2023 A. M. Borys, E. Hevia. License: This work is licensed under a Creative Commons Attribution 4.0 International License.