Alkali Metal Metal(ates) Containing Divalent Earth Abundant Transition Metals.
Alkali metals
Amides
Ate complexes
Cooperative effects
Transition metals
Journal
Chimia
ISSN: 0009-4293
Titre abrégé: Chimia (Aarau)
Pays: Switzerland
ID NLM: 0373152
Informations de publication
Date de publication:
27 Apr 2022
27 Apr 2022
Historique:
received:
02
02
2022
accepted:
22
02
2022
medline:
27
4
2022
pubmed:
27
4
2022
entrez:
9
12
2023
Statut:
epublish
Résumé
Recent advances in cooperative chemistry have shown the enormous potential of main group heterobimetallic complexes for the functionalisation of aromatic molecules. Going beyond main group metal chemistry, here we provide an overview on the synthesis, structure and reactivity of bimetallic complexes which combine an alkali-metal (AM= Li, Na) with a divalent earth-abundant transition metal (M= Mn, Fe, Co, Ni), containing the utility silyl amide HMDS (HMDS = N(SiMe3)2). Advancing the understanding on how cooperative effects operate in these bimetallic (ate) systems, selected examples of their applications in deprotonative metalation are also discussed with special emphasis on the constitution of the metalated intermediates.
Identifiants
pubmed: 38069775
doi: 10.2533/chimia.2022.336
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
336-340Subventions
Organisme : Swiss National Science Foundation
ID : 188753
Pays : Switzerland
Informations de copyright
Copyright 2022 Alessandra Logallo, Eva Hevia. License: This work is licensed under a Creative Commons Attribution 4.0 International License.