The effects of Cu-phenanthrene co-contamination on adsorption-desorption behaviors of phenanthrene in soils.
Adsorption-desorption
Cu-phenanthrene co-contamination
Phenanthrene
Soil
Journal
Chemosphere
ISSN: 1879-1298
Titre abrégé: Chemosphere
Pays: England
ID NLM: 0320657
Informations de publication
Date de publication:
14 Dec 2023
14 Dec 2023
Historique:
received:
16
10
2023
revised:
11
12
2023
accepted:
11
12
2023
medline:
17
12
2023
pubmed:
17
12
2023
entrez:
16
12
2023
Statut:
aheadofprint
Résumé
Polycyclic aromatic hydrocarbons (PAHs) are persistent organic pollutants in the environment, which are teratogenic, carcinogenic, and mutagenic. Co-contamination of PAHs and heavy metal commonly exists in soil. In this study, 20 types of soils with different properties in China were collected and comprehensively characterized. Phenanthrene (Phe) and Cu (II) were selected as representatives of PAHs and heavy metals, respectively. The adsorption-desorption behaviors of Phe under Phe contamination and Cu (II)-Phe co-contamination in 20 types of soils were studied. The adsorption-desorption behaviors of Phe in 20 types of soils varied greatly, and adsorption of Phe in the soils followed both linear partitioning and nonlinear surface adsorption. Soil organic matter (SOM) plays an important role in the adsorption-desorption behavior of Phe. When the concentrations of Phe were >50 μg/L, soft carbon (SC) fraction of SOM not black carbon (BC) contributed more to the adsorption of Phe. Soil dissolved organic matter (DOM), especially fulvic acid and humic acid fractions, contributes to the adsorption of Phe. Under the effect of Cu (II) (60 mg/L in solution), the adsorption capacity of soil for Phe increased, which possibly resulted from lowered pH, the existence of the cation-π bonding and the "bonding bridge" effect. The systematic investigation of adsorption-desorption behaviors of Phe in soils under heavy metal-PAHs co-contamination will provide a scientific basis for the calculation of soil environmental capacity in the future.
Identifiants
pubmed: 38103656
pii: S0045-6535(23)03224-1
doi: 10.1016/j.chemosphere.2023.140954
pii:
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
140954Informations de copyright
Copyright © 2023 Elsevier Ltd. All rights reserved.
Déclaration de conflit d'intérêts
Declaration of competing interest There is no conflict of interest exits in the submission of this manuscript, and manuscript is approved by all authors for publication. We declare that we have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this manuscript entitled “The effects of Cu-phenanthrene co-contamination on adsorption-desorption behaviors of phenanthrene in soils”.