Modeling the polychromism of oxide minerals: The case of alexandrite and cordierite.

TD‐DFT alexandrite cordierite iolite polychromism

Journal

Journal of computational chemistry
ISSN: 1096-987X
Titre abrégé: J Comput Chem
Pays: United States
ID NLM: 9878362

Informations de publication

Date de publication:
05 May 2024
Historique:
revised: 30 11 2023
received: 26 10 2023
accepted: 01 12 2023
medline: 26 12 2023
pubmed: 26 12 2023
entrez: 26 12 2023
Statut: ppublish

Résumé

In this work, we investigate the spectroscopic properties of photochromic alexandrite and cordierite by TD-DFT. The objective is to assess the TD-DFT for the simulation of pleochroism (change of color depending on the crystallographic direction of the observation) and the change of color as a function of the light source. For these simulations, we compared an embedding where dangling bonds are saturated by hydrogen atoms and an electrostatic embedding. The electrostatic embedding provided numerically more stable results and allowed a good reproduction of the pleochroism of cordierite, based on a Fe

Identifiants

pubmed: 38146809
doi: 10.1002/jcc.27288
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

834-842

Subventions

Organisme : Agence Nationale de la Recherche

Informations de copyright

© 2023 The Authors. Journal of Computational Chemistry published by Wiley Periodicals LLC.

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Auteurs

Raphaël Rullan (R)

ENS de Lyon, CNRS, Université Claude Bernard Lyon 1, Laboratoire de Chimie UMR 5182, Lyon, France.

Pauline Colinet (P)

ENS de Lyon, CNRS, Université Claude Bernard Lyon 1, Laboratoire de Chimie UMR 5182, Lyon, France.

Quentin Desdion (Q)

ENS de Lyon, CNRS, Université Claude Bernard Lyon 1, Laboratoire de Chimie UMR 5182, Lyon, France.

Stephan N Steinmann (SN)

ENS de Lyon, CNRS, Université Claude Bernard Lyon 1, Laboratoire de Chimie UMR 5182, Lyon, France.

Tangui Le Bahers (T)

ENS de Lyon, CNRS, Université Claude Bernard Lyon 1, Laboratoire de Chimie UMR 5182, Lyon, France.
Institut Universitaire de France, Paris, France.

Classifications MeSH