Lattice response to the radiation damage of molecular crystals: radiation-induced versus thermal expansivity.

disorder molecular crystals radiation damage thermal expansion

Journal

Acta crystallographica Section B, Structural science, crystal engineering and materials
ISSN: 2052-5206
Titre abrégé: Acta Crystallogr B Struct Sci Cryst Eng Mater
Pays: England
ID NLM: 101609037

Informations de publication

Date de publication:
01 Feb 2024
Historique:
medline: 4 1 2024
pubmed: 4 1 2024
entrez: 4 1 2024
Statut: aheadofprint

Résumé

The interaction of intense synchrotron radiation with molecular crystals frequently modifies the crystal structure by breaking bonds, producing fragments and, hence, inducing disorder. Here, a second-rank tensor of radiation-induced lattice strain is proposed to characterize the structural susceptibility to radiation. Quantitative estimates are derived using a linear response approximation from experimental data collected on three materials Hg(NO

Identifiants

pubmed: 38174727
pii: S2052520623010636
doi: 10.1107/S2052520623010636
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Informations de copyright

open access.

Auteurs

Chloe A Fuller (CA)

SNBL at ESRF, Grenoble France.

Emanuel Hupf (E)

University of Bremen, Department 2 - Biology/Chemistry, Leobener Str. 7, 29359 Bremen, Germany.

Lorraine A Malaspina (LA)

University of Bern, Department of Chemistry, Biochemistry and Pharmaceutical Sciences, Freiestrasse 3, 3012 Bern, Switzerland.

Simon Grabowsky (S)

University of Bern, Department of Chemistry, Biochemistry and Pharmaceutical Sciences, Freiestrasse 3, 3012 Bern, Switzerland.

Classifications MeSH