Effect of Antisolvent Additives in Aqueous Zinc Sulfate Electrolytes for Zinc Metal Anodes: The Case of Acetonitrile.

Journal

ACS energy letters
ISSN: 2380-8195
Titre abrégé: ACS Energy Lett
Pays: United States
ID NLM: 101697523

Informations de publication

Date de publication:
12 Jan 2024
Historique:
received: 20 11 2023
accepted: 01 12 2023
medline: 17 1 2024
pubmed: 17 1 2024
entrez: 17 1 2024
Statut: epublish

Résumé

Aqueous zinc-ion batteries (ZIBs) employing zinc metal anodes are gaining traction as batteries for moderate to long duration energy storage at scale. However, corrosion of the zinc metal anode through reaction with water limits battery efficiency. Much research in the past few years has focused on additives that decrease hydrogen evolution, but the precise mechanisms by which this takes place are often understudied and remain unclear. In this work, we study the role of an acetonitrile antisolvent additive in improving the performance of aqueous ZnSO

Identifiants

DOI: 10.1021/acsenergylett.3c02504 PMID: 38230374 PMC: PMC10789094
pubmed: 38230374
doi: 10.1021/acsenergylett.3c02504
pmc: PMC10789094
doi:

Types de publication

Journal Article

Langues

eng

Pagination

201-208

Informations de copyright

© 2023 UChicago Argonne, LLC, Operator of Argonne National Laboratory. Published by American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

Auteurs

Stefan Ilic (S)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Material Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.
ORCID: 0000-0002-6305-4001

Michael J Counihan (MJ)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Material Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.

Sydney N Lavan (SN)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Material Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.

Yingjie Yang (Y)

Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607, United States.
ORCID: 0000-0002-1898-8171

Yinke Jiang (Y)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States.

Diwash Dhakal (D)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195, United States.

Julian Mars (J)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States.

Emma N Antonio (EN)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States.

Luis Kitsu Iglesias (L)

Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States.
ORCID: 0000-0002-9292-4416

Timothy T Fister (TT)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.
ORCID: 0000-0001-6537-6170

Yong Zhang (Y)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States.
ORCID: 0000-0003-3988-5961

Edward J Maginn (EJ)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States.
ORCID: 0000-0002-6309-1347

Michael F Toney (MF)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States.
ORCID: 0000-0002-7513-1166

Robert F Klie (RF)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607, United States.
ORCID: 0000-0003-4773-6667

Justin G Connell (JG)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Material Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.
ORCID: 0000-0002-2979-2131

Sanja Tepavcevic (S)

Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, United States.
Material Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.
ORCID: 0000-0003-0151-8832

Classifications MeSH