Interaction of Organogermanium Compounds with Saccharides in Aqueous Solutions: Promotion of Aldose-to-ketose Isomerization and Its Molecular Mechanism.

Ge-132 aldose-ketose isomerization cis-diol structure continuous lactulose production dπ-pπ interaction ketose-organogermanium complex

Journal

Journal of applied glycoscience
ISSN: 1880-7291
Titre abrégé: J Appl Glycosci (1999)
Pays: Japan
ID NLM: 101167786

Informations de publication

Date de publication:
2023
Historique:
received: 11 05 2023
accepted: 28 07 2023
medline: 19 1 2024
pubmed: 19 1 2024
entrez: 19 1 2024
Statut: epublish

Résumé

This review discusses sugar isomerization with organogermanium compounds. Organogermanium compounds markedly increase the aldose-ketose (glucose-fructose or lactose-lactulose) isomerization ratio, double the initial reaction rate, and significantly reduce the base-catalyzed degradation of sugars.

Identifiants

pubmed: 38239765
doi: 10.5458/jag.jag.JAG-2023_0004
pmc: PMC10792222
doi:

Types de publication

Journal Article Review

Langues

eng

Pagination

81-97

Informations de copyright

2023 by The Japanese Society of Applied Glycoscience.

Déclaration de conflit d'intérêts

Takae Nagasawa is an employee of Asai Germanium Research Institute Co., Ltd., a company that specializes in the development, manufacture, and sales of Ge-132. Katsuyuki Sato was an employee of Asai Germanium Research Institute Co., Ltd. until May 2021.

Auteurs

Takae Nagasawa (T)

1 Asai Germanium Research Institute Co., Ltd.

Katsuyuki Sato (K)

1 Asai Germanium Research Institute Co., Ltd.

Takafumi Kasumi (T)

2 Enzymology and Molecular Biology Laboratory, Department of Chemistry and Life Science, Nihon University.

Classifications MeSH