New horizons on advanced nanoscale materials for Cultural Heritage conservation.

Nanomaterials have permeated numerous scientific and technological fields, and have gained growing importance over the past decades also in the preservation of Cultural Heritage. After a critical overview of the main nanomaterials adopted in art preservation, we provide new insights into some highly relevant gels, which constitute valuable tools to selectively remove dirt or other unwanted layers from the surface of works of art. In particular, the recent "twin-chain" gels, obtained by phase separation of two different PVAs and freeze-thawing, were considered as the most performing gel systems for the cleaning of Cultural Heritage. Three factors are crucial in determining the final gel properties,