Post-Transition-State Dynamic Effects in the Transmetalation of Pd(II)-F to Pd(II)-CF
Journal
JACS Au
ISSN: 2691-3704
Titre abrégé: JACS Au
Pays: United States
ID NLM: 101775714
Informations de publication
Date de publication:
22 Jan 2024
22 Jan 2024
Historique:
received:
17
11
2023
revised:
11
12
2023
accepted:
12
12
2023
medline:
26
1
2024
pubmed:
26
1
2024
entrez:
26
1
2024
Statut:
epublish
Résumé
The observation of post-transition-state dynamic effects in the context of metal-based transformation is rare. To date, there has been no reported case of a dynamic effect for the widely employed class of palladium-mediated coupling reactions. We performed an experimental and computational study of the trifluoromethylation of Pd
Identifiants
pubmed: 38274253
doi: 10.1021/jacsau.3c00724
pmc: PMC10806791
doi:
Types de publication
Journal Article
Langues
eng
Pagination
263-275Informations de copyright
© 2023 The Authors. Published by American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.