Light-induced MOF synthesis enabling composite photothermal materials.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
07 Feb 2024
Historique:
received: 09 02 2023
accepted: 17 01 2024
medline: 8 2 2024
pubmed: 8 2 2024
entrez: 7 2 2024
Statut: epublish

Résumé

Metal-organic frameworks (MOFs) are a class of porous materials known for their large surface areas. Thus, over the past few decades the development of MOFs and their applications has been a major topic of interest throughout the scientific community. However, many current conventional syntheses of MOFs are lengthy solvothermal processes carried out at elevated temperatures. Herein, we developed a rapid light-induced synthesis of MOFs by harnessing the plasmonic photothermal abilities of bipyramidal gold nanoparticles (AuBPs). The generality of the photo-induced method was demonstrated by synthesizing four different MOFs utilizing three different wavelengths (520 nm, 660 nm and 850 nm). Furthermore, by regulating light exposure, AuBPs could be embedded in the MOF or maintained in the supernatant. Notably, the AuBPs-embedded MOF (AuBP@UIO-66) retained its plasmonic properties along with the extraordinary surface area typical to MOFs. The photothermal AuBP@UIO-66 demonstrated a significant light-induced heating response that was utilized for ultrafast desorption and MOF activation.

Identifiants

pubmed: 38326307
doi: 10.1038/s41467-024-45333-9
pii: 10.1038/s41467-024-45333-9
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1154

Subventions

Organisme : Israel Science Foundation (ISF)
ID : 2491/20

Informations de copyright

© 2024. The Author(s).

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Auteurs

Ofir Shelonchik (O)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

Nir Lemcoff (N)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

Ran Shimoni (R)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

Aritra Biswas (A)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

Elad Yehezkel (E)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

Doron Yesodi (D)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

Idan Hod (I)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.
Ilse Katz Institute for Nanotechnology Science, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.
Goldman Sonnenfeldt School of Sustainability and Climate Change, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel.

Yossi Weizmann (Y)

Department of Chemistry, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel. yweizmann@bgu.ac.il.
Ilse Katz Institute for Nanotechnology Science, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel. yweizmann@bgu.ac.il.
Goldman Sonnenfeldt School of Sustainability and Climate Change, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel. yweizmann@bgu.ac.il.

Classifications MeSH