Assignment of individual structures from intermetalloid nickel gallium cluster ensembles.
Journal
Communications chemistry
ISSN: 2399-3669
Titre abrégé: Commun Chem
Pays: England
ID NLM: 101725670
Informations de publication
Date de publication:
13 Feb 2024
13 Feb 2024
Historique:
received:
14
07
2023
accepted:
19
01
2024
medline:
14
2
2024
pubmed:
14
2
2024
entrez:
13
2
2024
Statut:
epublish
Résumé
Poorly selective mixed-metal cluster synthesis and separation yield reaction solutions of inseparable intermetalloid cluster mixtures, which are often discarded. High-resolution mass spectrometry, however, can provide precise compositional data of such product mixtures. Structure assignments can be achieved by advanced computational screening and consideration of the complete structural space. Here, we experimentally verify structure and composition of a whole cluster ensemble by combining a set of spectroscopic techniques. Our study case are the very similar nickel/gallium clusters of M
Identifiants
pubmed: 38351167
doi: 10.1038/s42004-024-01110-9
pii: 10.1038/s42004-024-01110-9
doi:
Types de publication
Journal Article
Langues
eng
Pagination
29Subventions
Organisme : Deutsche Forschungsgemeinschaft (German Research Foundation)
ID : FI-502/44-1
Informations de copyright
© 2024. The Author(s).
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