Influence of pump laser fluence on ultrafast myoglobin structural dynamics.


Journal

Nature
ISSN: 1476-4687
Titre abrégé: Nature
Pays: England
ID NLM: 0410462

Informations de publication

Date de publication:
14 Feb 2024
Historique:
received: 22 11 2022
accepted: 04 01 2024
medline: 15 2 2024
pubmed: 15 2 2024
entrez: 14 2 2024
Statut: aheadofprint

Résumé

High-intensity femtosecond pulses from an X-ray free-electron laser enable pump-probe experiments for the investigation of electronic and nuclear changes during light-induced reactions. On timescales ranging from femtoseconds to milliseconds and for a variety of biological systems, time-resolved serial femtosecond crystallography (TR-SFX) has provided detailed structural data for light-induced isomerization, breakage or formation of chemical bonds and electron transfer

Identifiants

pubmed: 38355794
doi: 10.1038/s41586-024-07032-9
pii: 10.1038/s41586-024-07032-9
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Informations de copyright

© 2024. The Author(s).

Références

Barends, T. R. M., Stauch, B., Cherezov, V. & Schlichting, I. Serial femtosecond crystallography. Nat. Rev. Meth. Primers 2, 59 (2022).
doi: 10.1038/s43586-022-00141-7
Chapman, H. N. X-ray free-electron lasers for the structure and dynamics of macromolecules. Annu. Rev. Biochem. 88, 35–58 (2019).
pubmed: 30601681 doi: 10.1146/annurev-biochem-013118-110744
Barends, T. R. et al. Direct observation of ultrafast collective motions in CO myoglobin upon ligand dissociation. Science 350, 445–450 (2015).
pubmed: 26359336 doi: 10.1126/science.aac5492
Pande, K. et al. Femtosecond structural dynamics drives the trans/cis isomerization in photoactive yellow protein. Science 352, 725–729 (2016).
pubmed: 27151871 pmcid: 5291079 doi: 10.1126/science.aad5081
Coquelle, N. et al. Chromophore twisting in the excited state of a photoswitchable fluorescent protein captured by time-resolved serial femtosecond crystallography. Nat. Chem. 10, 31–37 (2018).
pubmed: 29256511 doi: 10.1038/nchem.2853
Nogly, P. et al. Retinal isomerization in bacteriorhodopsin captured by a femtosecond x-ray laser. Science 361, eaat0094 (2018).
pubmed: 29903883 doi: 10.1126/science.aat0094
Nass Kovacs, G. et al. Three-dimensional view of ultrafast dynamics in photoexcited bacteriorhodopsin. Nat. Commun. 10, 3177 (2019).
pubmed: 31320619 pmcid: 6639342 doi: 10.1038/s41467-019-10758-0
Claesson, E. et al. The primary structural photoresponse of phytochrome proteins captured by a femtosecond X-ray laser. eLife 9, e53514 (2020).
pubmed: 32228856 pmcid: 7164956 doi: 10.7554/eLife.53514
Skopintsev, P. et al. Femtosecond-to-millisecond structural changes in a light-driven sodium pump. Nature 583, 314–318 (2020).
pubmed: 32499654 doi: 10.1038/s41586-020-2307-8
Yun, J. H. et al. Early-stage dynamics of chloride ion-pumping rhodopsin revealed by a femtosecond X-ray laser. Proc. Natl Acad. Sci. USA 118, e2020486118 (2021).
pubmed: 33753488 pmcid: 8020794 doi: 10.1073/pnas.2020486118
Dods, R. et al. Ultrafast structural changes within a photosynthetic reaction centre. Nature 589, 310–314 (2021).
pubmed: 33268896 doi: 10.1038/s41586-020-3000-7
Mous, S. et al. Dynamics and mechanism of a light-driven chloride pump. Science 375, 845–851 (2022).
pubmed: 35113649 doi: 10.1126/science.abj6663
Maestre-Reyna, M. et al. Serial crystallography captures dynamic control of sequential electron and proton transfer events in a flavoenzyme. Nat. Chem. 14, 677–685 (2022).
pubmed: 35393554 doi: 10.1038/s41557-022-00922-3
Gruhl, T. et al. Utrafast structural changes direct the first molecular events of vision. Nature 615, 939–944 (2023).
pubmed: 36949205 pmcid: 10060157 doi: 10.1038/s41586-023-05863-6
Wranik, M. et al. Watching the release of a photopharmacological drug from tubulin using time-resolved serial crystallography. Nat. Commun. 14, 903 (2023).
pubmed: 36807348 pmcid: 9936131 doi: 10.1038/s41467-023-36481-5
Fadini, A. et al. Serial femtosecond crystallography reveals that photoactivation in a fluorescent protein proceeds via the Hula Twist mechanism. J. Am. Chem. Soc. 145, 15796–15808 (2023).
pubmed: 37418747 pmcid: 10375524 doi: 10.1021/jacs.3c02313
Hutchison, C. D. M. et al. Optical control of ultrafast structural dynamics in a fluorescent protein. Nat. Chem. 15, 1607–1615 (2023).
pubmed: 37563326 pmcid: 10624617 doi: 10.1038/s41557-023-01275-1
Miller, R. J. D., Pare-Labrosse, O., Sarracini, A. & Besaw, J. E. Three-dimensional view of ultrafast dynamics in photoexcited bacteriorhodopsin in the multiphoton regime and biological relevance. Nat. Commun. 11, 1240 (2020).
pubmed: 32144255 pmcid: 7060340 doi: 10.1038/s41467-020-14971-0
Besaw, J. E. & Miller, R. J. D. Addressing high excitation conditions in time-resolved X-ray diffraction experiments and issues of biological relevance. Curr. Opin. Struct. Biol. 81, 102624 (2023).
pubmed: 37331203 doi: 10.1016/j.sbi.2023.102624
Brändén, G. & Neutze, R. Advances and challenges in time-resolved macromolecular crystallography. Science 373, eaba0954 (2021).
pubmed: 34446579 doi: 10.1126/science.aba0954
Falahati, K., Tamura, H., Burghardt, I. & Huix-Rotllant, M. Ultrafast carbon monoxide photolysis and heme spin-crossover in myoglobin via nonadiabatic quantum dynamics. Nat. Commun. 9, 4502 (2018).
pubmed: 30374057 pmcid: 6206034 doi: 10.1038/s41467-018-06615-1
Maestre-Reyna, M. et al. Visualizing the DNA repair process by a photolyase at atomic resolution. Science 382, eadd7795 (2023).
pubmed: 38033054 doi: 10.1126/science.add7795
Christou, N. E. et al. Time-resolved crystallography captures light-driven DNA repair. Science 382, 1015–1020 (2023).
pubmed: 38033070 doi: 10.1126/science.adj4270
Sorigue, D. et al. Mechanism and dynamics of fatty acid photodecarboxylase. Science 372, eabd5687 (2021).
pubmed: 33833098 doi: 10.1126/science.abd5687
Hughes, J. Phytochrome photoreceptors: rapid response. eLife 9, e57105 (2021).
doi: 10.7554/eLife.57105
Grünbein, M. L. et al. Illumination guidelines for ultrafast pump-probe experiments by serial femtosecond crystallography. Nat. Methods 17, 681–684 (2020).
pubmed: 32451477 doi: 10.1038/s41592-020-0847-3
Genberg, L., Richard, L., Mclendon, G. & Miller, R. J. D. Direct observation of global protein motion in hemoglobin and myoglobin on picosecond time scales. Science 251, 1051–1054 (1991).
pubmed: 1998121 doi: 10.1126/science.1998121
Goodno, G. D., Astinov, V. & Miller, R. J. D. Femtosecond heterodyne-detected four-wave-mixing studies of deterministic protein motions. 2. Protein response. J. Phys. Chem. A 103, 10630–10643 (1999).
doi: 10.1021/jp993559y
Carrillo, M. et al. High-resolution crystal structures of transient intermediates in the phytochrome photocycle. Structure 29, 743–754 e4 (2021).
pubmed: 33756101 pmcid: 8405169 doi: 10.1016/j.str.2021.03.004
Hadjidemetriou, K. et al. Time-resolved serial femtosecond crystallography on fatty-acid photodecarboxylase: lessons learned. Acta Crystallogr. D 78, 1131–1142 (2022).
doi: 10.1107/S2059798322007525
Franzen, S., Kiger, L., Poyart, C. & Martin, J. L. Heme photolysis occurs by ultrafast excited state metal-to-ring charge transfer. Biophys. J. 80, 2372–2385 (2001).
pubmed: 11325737 pmcid: 1301426 doi: 10.1016/S0006-3495(01)76207-8
Lim, M. H., Jackson, T. A. & Anfinrud, P. A. Femtosecond near-IR absorbance study of photoexcited myoglobin: dynamics of electronic and thermal relaxation. J. Phys. Chem. A 100, 12043–12051 (1996).
Levantino, M. et al. Observing heme doming in myoglobin with femtosecond X-ray absorption spectroscopy. Struct. Dyn. 2, 041713 (2015).
pubmed: 26798812 pmcid: 4711634 doi: 10.1063/1.4921907
Mizutani, Y. & Kitagawa, T. Ultrafast dynamics of myoglobin probed by time-resolved resonance Raman spectroscopy. Chem. Rec. 1, 258–275 (2001).
pubmed: 11895123 doi: 10.1002/tcr.1012
Shelby, M. L. et al. Interplays of electron and nuclear motions along CO dissociation trajectory in myoglobin revealed by ultrafast X-rays and quantum dynamics calculations. Proc. Natl Acad. Sci. USA 118, e2018966118 (2021).
pubmed: 33782122 pmcid: 8040624 doi: 10.1073/pnas.2018966118
Guallar, V., Jarzecki, A. A., Friesner, R. A. & Spiro, T. G. Modeling of ligation-induced helix/loop displacements in myoglobin: toward an understanding of hemoglobin allostery. J. Am. Chem. Soc. 128, 5427–5435 (2006).
pubmed: 16620114 doi: 10.1021/ja057318h
Kenkre, V. M., Tokmakoff, A. & Fayer, M. D. Theory of vibrational-relaxation of polyatomic-molecules in liquids. J. Chem. Phys. 101, 10618–10629 (1994).
doi: 10.1063/1.467876
Rosca, F. et al. Investigations of anharmonic low-frequency oscillations in heme proteins. J. Phys. Chem. A 106, 3540–3552 (2002).
doi: 10.1021/jp0129277
Lian, T. Q., Locke, B., Kholodenko, Y. & Hochstrasser, R. M. Energy-flow from solute to solvent probed by femtosecond IR spectroscopy - malachite green and heme protein solutions. J. Phys. Chem. 98, 11648–11656 (1994).
doi: 10.1021/j100096a005
Miller, R. J. D. Energetics and dynamics of deterministic protein motion. Acc. Chem. Res. 27, 145–150 (1994).
doi: 10.1021/ar00041a005
Heyne, K. Impact of ultrafast electric field changes on photoreceptor protein dynamics. J. Phys. Chem. B 126, 581–587 (2022).
pubmed: 35026113 doi: 10.1021/acs.jpcb.1c08131
Champion, P. M. Chemistry - following the flow of energy in biomolecules. Science 310, 980–982 (2005).
pubmed: 16284167 pmcid: 2767379 doi: 10.1126/science.1120280
Hutchison, C. D. M. et al. Photocycle populations with femtosecond excitation of crystalline photoactive yellow protein. Chem. Phys. Lett. 654, 63–71 (2016).
doi: 10.1016/j.cplett.2016.04.087
Arnlund, D. et al. Visualizing a protein quake with time-resolved X-ray scattering at a free-electron laser. Nat. Methods 11, 923–926 (2014).
pubmed: 25108686 pmcid: 4149589 doi: 10.1038/nmeth.3067
Seno, Y. & Go, N. Deoxymyoglobin studied by the conformational normal mode analysis. I. Dynamics of globin and the heme-globin interaction. J. Mol. Biol. 216, 95–109 (1990).
pubmed: 2231732 doi: 10.1016/S0022-2836(05)80063-4
Gorel, A., Schlichting, I. & Barends, T. R. M. Discerning best practices in XFEL-based biological crystallography - standards for nonstandard experiments. IUCrJ 8, 532–543 (2021).
pubmed: 34258002 pmcid: 8256713 doi: 10.1107/S205225252100467X
Grünbein, M. L. et al. Effect of X-ray free-electron laser-induced shockwaves on haemoglobin microcrystals delivered in a liquid je. Nat. Commun. 12, 1672 (2021).
pubmed: 33723266 pmcid: 7960726 doi: 10.1038/s41467-021-21819-8
Shoeman, R. L., Hartmann, E. & Schlichting, I. Growing and making nano- and microcrystals. Nat. Protoc. 18, 854–882 (2023).
pubmed: 36451055 doi: 10.1038/s41596-022-00777-5
Kedenburg, S., Vieweg, M., Gissibl, T. & Giessen, H. Linear refractive index and absorption measurements of nonlinear optical liquids in the visible and near-infrared spectral region. Opt. Mater. Express 2, 1588–1611 (2012).
doi: 10.1364/OME.2.001588
Milne, C. J. et al. Opportunities for chemistry at the SwissFEL X-ray free electron laser. Chimia 71, 299–307 (2017).
pubmed: 28576157 doi: 10.2533/chimia.2017.299
Weierstall, U., Spence, J. C. & Doak, R. B. Injector for scattering measurements on fully solvated biospecies. Rev. Sci. Instrum. 83, 035108 (2012).
pubmed: 22462961 doi: 10.1063/1.3693040
Nass, K. et al. Structural dynamics in proteins induced by and probed with X-ray free-electron laser pulses. Nat. Commun. 11, 1814 (2020).
pubmed: 32286284 pmcid: 7156470 doi: 10.1038/s41467-020-15610-4
White, T. A. et al. CrystFEL: a software suite for snapshot serial crystallography. J. Appl. Crystallogr. 45, 335–341 (2012).
doi: 10.1107/S0021889812002312
Gevorkov, Y. et al. XGANDALF - extended gradient descent algorithm for lattice finding. Acta Crystallogr. A 75, 694–704 (2019).
doi: 10.1107/S2053273319010593
Duisenberg, A. J. M. Indexing in single-crystal diffractometry with an obstinate list of reflections. J. Appl. Crystallogr. 25, 92–96 (1992).
doi: 10.1107/S0021889891010634
Kabsch, W. XDS. Acta Crystallogr. D 66, 125–132 (2010).
pubmed: 20124692 pmcid: 2815665 doi: 10.1107/S0907444909047337
Leslie, A. G. W. The integration of macromolecular diffraction data. Acta Crystallogr. D 62, 48–57 (2006).
pubmed: 16369093 doi: 10.1107/S0907444905039107
Kirian, R. A. et al. Femtosecond protein nanocrystallography—data analysis methods. Opt. Express 18, 5713–5723 (2010).
pubmed: 20389587 doi: 10.1364/OE.18.005713
Kirian, R. A. et al. Structure-factor analysis of femtosecond microdiffraction patterns from protein nanocrystals. Acta Crystallogr. A 67, 131–140 (2011).
pubmed: 21325716 pmcid: 3066792 doi: 10.1107/S0108767310050981
Howell, L. & Smith, D. Normal probability analysis. J. Appl. Crystallogr. 25, 81–86 (1992).
doi: 10.1107/S0021889891010385
Collaborative Computational Project Nr. 4. The CCP4 suite: programs for protein crystallography. Acta Crystallogr. D 50, 760–763 (1994).
doi: 10.1107/S0907444994003112
Genick, U. K. et al. Structure of a protein photocycle intermediate by millisecond time-resolved crystallography. Science 275, 1471–1475 (1997).
pubmed: 9045611 doi: 10.1126/science.275.5305.1471
Genick, U. K. Structure-factor extrapolation using the scalar approximation: theory, applications and limitations. Acta Crystallogr. D 63, 1029–1041 (2007).
pubmed: 17881820 doi: 10.1107/S0907444907038164
Adams, P. D. et al. PHENIX: a comprehensive Python-based system for macromolecular structure solution. Acta Crystallogr. D 66, 213–21 (2010).
pubmed: 20124702 pmcid: 2815670 doi: 10.1107/S0907444909052925
Emsley, P. & Cowtan, K. Coot: model-building tools for molecular graphics. Acta Crystallogr. D 60, 2126–2132 (2004).
pubmed: 15572765 doi: 10.1107/S0907444904019158
Emsley, P., Lohkamp, B., Scott, W. G. & Cowtan, K. Features and development of Coot. Acta Crystallogr. D 66, 486–501 (2010).
pubmed: 20383002 pmcid: 2852313 doi: 10.1107/S0907444910007493
DeLano, W. L. PyMol. http://www.pymol.org (2002).
Harris, C. R. et al. Array programming with NumPy. Nature 585, 357–362 (2020).
pubmed: 32939066 pmcid: 7759461 doi: 10.1038/s41586-020-2649-2
Virtanen, P. et al. SciPy 1.0: fundamental algorithms for scientific computing in Python. Nat. Methods 17, 352–352 (2020).
pubmed: 32094914 pmcid: 7056641 doi: 10.1038/s41592-020-0772-5
Galvan, I. F. et al. OpenMolcas: from source code to insight. J. Chem. Theory Comput. 15, 5925–5964 (2019).
doi: 10.1021/acs.jctc.9b00532
Aquilante, F. et al. Modern quantum chemistry with [Open]Molcas. J. Chem. Phys. 152, 214117 (2020).
pubmed: 32505150 doi: 10.1063/5.0004835
Chu, K. et al. Structure of a ligand-binding intermediate in wild-type carbonmonoxy myoglobin. Nature 403, 921–923 (2000).
pubmed: 10706294 doi: 10.1038/35002641
Rackers, J. A. et al. Tinker 8: software tools for molecular design. J. Chem. Theory Comput. 14, 5273–5289 (2018).
pubmed: 30176213 pmcid: 6335969 doi: 10.1021/acs.jctc.8b00529
Barca, G. M. J. et al. Recent developments in the general atomic and molecular electronic structure system. J. Chem. Phys. 152, 154102 (2020).
pubmed: 32321259 doi: 10.1063/5.0005188
Huang, J. et al. CHARMM36m: an improved force field for folded and intrinsically disordered proteins. Nat. Methods 14, 71–73 (2017).
pubmed: 27819658 doi: 10.1038/nmeth.4067

Auteurs

Thomas R M Barends (TRM)

Max Planck Institute for Medical Research, Heidelberg, Germany. Thomas.Barends@mpimf-heidelberg.mpg.de.

Alexander Gorel (A)

Max Planck Institute for Medical Research, Heidelberg, Germany.

Swarnendu Bhattacharyya (S)

Institut de Chimie Radicalaire, CNRS, Aix Marseille Univ, Marseille, France.

Giorgio Schirò (G)

Institut de Biologie Structurale, Université Grenoble Alpes, CEA, CNRS, Grenoble, France.

Camila Bacellar (C)

Paul Scherrer Institute, Villigen, Switzerland.

Claudio Cirelli (C)

Paul Scherrer Institute, Villigen, Switzerland.

Jacques-Philippe Colletier (JP)

Institut de Biologie Structurale, Université Grenoble Alpes, CEA, CNRS, Grenoble, France.

Lutz Foucar (L)

Max Planck Institute for Medical Research, Heidelberg, Germany.

Marie Luise Grünbein (ML)

Max Planck Institute for Medical Research, Heidelberg, Germany.

Elisabeth Hartmann (E)

Max Planck Institute for Medical Research, Heidelberg, Germany.

Mario Hilpert (M)

Max Planck Institute for Medical Research, Heidelberg, Germany.

James M Holton (JM)

Molecular Biophysics and Integrated Bioimaging Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA.

Philip J M Johnson (PJM)

Paul Scherrer Institute, Villigen, Switzerland.

Marco Kloos (M)

European XFEL GmbH, Schenefeld, Germany.

Gregor Knopp (G)

Paul Scherrer Institute, Villigen, Switzerland.

Bogdan Marekha (B)

ENSL, CNRS, Laboratoire de Chimie UMR 5182, Lyon, France.

Karol Nass (K)

Paul Scherrer Institute, Villigen, Switzerland.

Gabriela Nass Kovacs (G)

Max Planck Institute for Medical Research, Heidelberg, Germany.

Dmitry Ozerov (D)

Paul Scherrer Institute, Villigen, Switzerland.

Miriam Stricker (M)

Department of Statistics, University of Oxford, Oxford, UK.

Martin Weik (M)

Institut de Biologie Structurale, Université Grenoble Alpes, CEA, CNRS, Grenoble, France.

R Bruce Doak (RB)

Max Planck Institute for Medical Research, Heidelberg, Germany.

Robert L Shoeman (RL)

Max Planck Institute for Medical Research, Heidelberg, Germany.

Christopher J Milne (CJ)

Paul Scherrer Institute, Villigen, Switzerland.

Miquel Huix-Rotllant (M)

Institut de Chimie Radicalaire, CNRS, Aix Marseille Univ, Marseille, France. miquel.huixrotllant@univ-amu.fr.

Marco Cammarata (M)

ESRF, Grenoble, France.

Ilme Schlichting (I)

Max Planck Institute for Medical Research, Heidelberg, Germany. ilme.schlichting@mpimf-heidelberg.mpg.de.

Classifications MeSH