Nickel-organo compounds as potential enzyme precursors under simulated early Earth conditions.
Journal
Communications chemistry
ISSN: 2399-3669
Titre abrégé: Commun Chem
Pays: England
ID NLM: 101725670
Informations de publication
Date de publication:
15 Feb 2024
15 Feb 2024
Historique:
received:
21
10
2023
accepted:
01
02
2024
medline:
16
2
2024
pubmed:
16
2
2024
entrez:
16
2
2024
Statut:
epublish
Résumé
The transition from inorganic catalysis through minerals to organic catalysis by enzymes is a necessary step in the emergence of life. Our work is elucidating likely reactions at the earliest moments of Life, prior to the existence of enzymatic catalysis, by exploring essential intersections between nickel bioinorganic chemistry and pterin biochemistry. We used a prebiotically-inspired acetylene-containing volcanic hydrothermal experimental environment to shed light on the efficient formation of nickel-organo complexes. The simplest bis(dithiolene)nickel complex (C
Identifiants
pubmed: 38361005
doi: 10.1038/s42004-024-01119-0
pii: 10.1038/s42004-024-01119-0
doi:
Types de publication
Journal Article
Langues
eng
Pagination
33Informations de copyright
© 2024. The Author(s).
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