Exploration of newly synthesized amantadine-thiourea conjugates for their DNA binding, anti-elastase, and anti-glioma potentials.

Amantadine-thiourea conjugates Anti-elastase activity Cytotoxicity for normal & cancerous cells DFT/docking Spectroscopic/electrochemical DNA binding

Journal

International journal of biological macromolecules
ISSN: 1879-0003
Titre abrégé: Int J Biol Macromol
Pays: Netherlands
ID NLM: 7909578

Informations de publication

Date de publication:
16 Feb 2024
Historique:
received: 20 11 2023
revised: 12 02 2024
accepted: 14 02 2024
medline: 19 2 2024
pubmed: 19 2 2024
entrez: 18 2 2024
Statut: aheadofprint

Résumé

Three newly synthesized amantadine thiourea conjugates namely MS-1 N-(((3 s,5 s,7 s)-adamantan-1-yl)carbamothioyl)benzamide, MS-2 N-(((3 s,5 s,7 s)-adamantan-1-yl)carbamothioyl)-4-methylbenzamide and MS-3 N-((3 s,5 s,7 s)-adamantan-1-ylcarbamothioyl)-4-chlorobenzamide were investigated for their structures, bindings (DNA/ elastase), and for their impact on healthy and cancerous cells. Theoretical (DFT/docking) and experimental {UV-visible (UV-), fluorescence (Flu-), and cyclic voltammetry (CV)} studies indicated binding interactions of each conjugate with DNA and elastase enzyme. Theoretically and experimentally calculated binding parameters for conjugate - DNA interaction revealed MS-3 - DNA to have most significant binding with comparatively greater values of binding parameters {(K

Identifiants

pubmed: 38368975
pii: S0141-8130(24)01034-1
doi: 10.1016/j.ijbiomac.2024.130231
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

130231

Informations de copyright

Copyright © 2024 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of competing interest The authors would like to declare that there is no established conflict of interest.

Auteurs

Nasima Arshad (N)

Department of Chemistry, Allama Iqbal Open University, 44000 Islamabad, Pakistan. Electronic address: nasima.arshad@aiou.edu.pk.

Muhammad Shakeel (M)

Department of Chemistry, Allama Iqbal Open University, 44000 Islamabad, Pakistan.

Aneela Javed (A)

Healthcare Biotechnology, Atta-ur-Rehman School of Applied Biosciences, National University of Sciences & Technology- NUST, 44000 Islamabad, Pakistan.

Fouzia Perveen (F)

School of Interdisciplinary Engineering and Sciences (SINES), National University of Sciences & Technology - NUST, 44000 Islamabad, Pakistan.

Aamer Saeed (A)

Department of Chemistry, Quaid-i-Azam University, 45320 Islamabad, Pakistan.

Atteeque Ahmed (A)

Department of Chemistry, Quaid-i-Azam University, 45320 Islamabad, Pakistan.

Hammad Ismail (H)

Department of Biochemistry & Biotechnology, University of Gujrat, 50700 Gujrat, Pakistan.

Pervaiz Ali Channar (PA)

Department of Basic Sciences and Humanities, Dawood University of Engineering and Technology Karachi, Karachi, Pakistan.

Fatima Naseer (F)

School of Interdisciplinary Engineering and Sciences (SINES), National University of Sciences & Technology - NUST, 44000 Islamabad, Pakistan.

Classifications MeSH