Tunable valence tautomerism in lanthanide-organic alloys.
Journal
Nature chemistry
ISSN: 1755-4349
Titre abrégé: Nat Chem
Pays: England
ID NLM: 101499734
Informations de publication
Date de publication:
19 Feb 2024
19 Feb 2024
Historique:
received:
08
08
2023
accepted:
12
12
2023
medline:
20
2
2024
pubmed:
20
2
2024
entrez:
20
2
2024
Statut:
aheadofprint
Résumé
The inimitable electronic structures of the lanthanide (Ln) ions are key to advanced materials and technologies involving these elements. The trivalent ions are ubiquitous and are used much more widely than the divalent and tetravalent analogues, which possess vastly different optical and magnetic properties. Hence, alteration of the valence electron count by external stimuli can lead to dramatic changes in materials properties. Compounds exhibiting a temperature-induced complete Ln(III) ⇄ Ln(II) switch, referred to as a valence tautomeric (VT) transition, are rare. Here we present an abrupt and hysteretic VT transition in a lanthanide-based coordination polymer, SmI
Identifiants
pubmed: 38374454
doi: 10.1038/s41557-023-01422-8
pii: 10.1038/s41557-023-01422-8
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : Villum Fonden (Villum Foundation)
ID : 42094
Organisme : Det Frie Forskningsråd (Danish Council for Independent Research)
ID : 0165-00073B
Organisme : Carlsbergfondet (Carlsberg Foundation)
ID : CF17-0637
Informations de copyright
© 2024. The Author(s), under exclusive licence to Springer Nature Limited.
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