Ferromagnetism on an atom-thick & extended 2D metal-organic coordination network.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
29 Feb 2024
Historique:
received: 06 03 2023
accepted: 14 02 2024
medline: 1 3 2024
pubmed: 1 3 2024
entrez: 29 2 2024
Statut: epublish

Résumé

Ferromagnetism is the collective alignment of atomic spins that retain a net magnetic moment below the Curie temperature, even in the absence of external magnetic fields. Reducing this fundamental property into strictly two-dimensions was proposed in metal-organic coordination networks, but thus far has eluded experimental realization. In this work, we demonstrate that extended, cooperative ferromagnetism is feasible in an atomically thin two-dimensional metal-organic coordination network, despite only ≈ 5% of the monolayer being composed of Fe atoms. The resulting ferromagnetic state exhibits an out-of-plane easy-axis square-like hysteresis loop with large coercive fields over 2 Tesla, significant magnetic anisotropy, and persists up to T

Identifiants

pubmed: 38424075
doi: 10.1038/s41467-024-46115-z
pii: 10.1038/s41467-024-46115-z
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1858

Subventions

Organisme : Ministry of Economy and Competitiveness | Agencia Estatal de Investigación (Spanish Agencia Estatal de Investigación)
ID : PID2019-107338RB-C64
Organisme : Ministry of Economy and Competitiveness | Agencia Estatal de Investigación (Spanish Agencia Estatal de Investigación)
ID : PID2022-138750NB-C21

Informations de copyright

© 2024. The Author(s).

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Auteurs

Jorge Lobo-Checa (J)

Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, 50009, Zaragoza, Spain. jorge.lobo@csic.es.
Departamento de Física de la Materia Condensada, Universidad de Zaragoza, E-50009, Zaragoza, Spain. jorge.lobo@csic.es.

Leyre Hernández-López (L)

Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, 50009, Zaragoza, Spain.
Departamento de Física de la Materia Condensada, Universidad de Zaragoza, E-50009, Zaragoza, Spain.

Mikhail M Otrokov (MM)

Centro de Física de Materiales CSIC/UPV-EHU-Materials Physics Center, Manuel Lardizabal 5, E-20018, San Sebastián, Spain. mikhail.otrokov@csic.es.
Donostia International Physics Center, Paseo Manuel de Lardizabal 4, E-20018, San Sebastian, Spain. mikhail.otrokov@csic.es.
IKERBASQUE, Basque Foundation for Science, E-48011, Bilbao, Spain. mikhail.otrokov@csic.es.
Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, Zaragoza, 50009, Spain. mikhail.otrokov@csic.es.

Ignacio Piquero-Zulaica (I)

Physics Department E20, Technical University of Munich, 85748, Garching, Germany.

Adriana E Candia (AE)

Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, 50009, Zaragoza, Spain.
Instituto de Desarrollo Tecnológico para la Industria Química (INTEC-UNL-CONICET), 3000, Santa Fe, Argentina.
Instituto de Física del Litoral, Universidad Nacional del Litoral (IFIS-UNL-CONICET), 3000, Santa Fe, Argentina.

Pierluigi Gargiani (P)

ALBA Synchrotron Light Source, E-08290, Cerdanyola del Vallès, Spain.

David Serrate (D)

Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, 50009, Zaragoza, Spain.
Departamento de Física de la Materia Condensada, Universidad de Zaragoza, E-50009, Zaragoza, Spain.

Fernando Delgado (F)

Instituto de Estudios Avanzados IUDEA, Departamento de Física, Universidad de La Laguna, C/Astrofísico Francisco Sánchez, s/n, 38203, La Laguna, Spain.

Manuel Valvidares (M)

ALBA Synchrotron Light Source, E-08290, Cerdanyola del Vallès, Spain.

Jorge Cerdá (J)

Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, 28049, Madrid, Spain.

Andrés Arnau (A)

Centro de Física de Materiales CSIC/UPV-EHU-Materials Physics Center, Manuel Lardizabal 5, E-20018, San Sebastián, Spain. andres.arnau@ehu.eus.
Donostia International Physics Center, Paseo Manuel de Lardizabal 4, E-20018, San Sebastian, Spain. andres.arnau@ehu.eus.
Departamento de Polímeros y Materiales Avanzados: Física, Química y Tecnología, Facultad de Química UPV/EHU, 20080, Donostia-San Sebastián, Spain. andres.arnau@ehu.eus.

Fernando Bartolomé (F)

Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, 50009, Zaragoza, Spain. fernando.bartolome@csic.es.
Departamento de Física de la Materia Condensada, Universidad de Zaragoza, E-50009, Zaragoza, Spain. fernando.bartolome@csic.es.

Classifications MeSH