Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways.
C−H activation
carbon nitrides
chromoselectivity
photobiocatalysis
unspecific peroxygenases
Journal
Angewandte Chemie (Weinheim an der Bergstrasse, Germany)
ISSN: 0044-8249
Titre abrégé: Angew Chem Weinheim Bergstr Ger
Pays: Germany
ID NLM: 100955692
Informations de publication
Date de publication:
22 Mar 2021
22 Mar 2021
Historique:
received:
05
01
2021
medline:
22
3
2021
pubmed:
22
3
2021
entrez:
20
3
2024
Statut:
ppublish
Résumé
Controlling the selectivity of a chemical reaction with external stimuli is common in thermal processes, but rare in visible-light photocatalysis. Here we show that the redox potential of a carbon nitride photocatalyst (CN-OA-m) can be tuned by changing the irradiation wavelength to generate electron holes with different oxidation potentials. This tuning was the key to realizing photo-chemo-enzymatic cascades that give either the ( Green or blue? The wavelength controls the outcome. Chromoselective activation of a carbon nitride generates electron holes with different oxidation potentials that are used for selective oxidation processes. By coupling the photocatalytic reactions with biocatalysis the (
Autres résumés
Type: Publisher
(ger)
Green or blue? The wavelength controls the outcome. Chromoselective activation of a carbon nitride generates electron holes with different oxidation potentials that are used for selective oxidation processes. By coupling the photocatalytic reactions with biocatalysis the (
Identifiants
pubmed: 38504955
doi: 10.1002/ange.202100164
pii: ANGE202100164
pmc: PMC10946972
doi:
Types de publication
Journal Article
Langues
eng
Pagination
7041-7045Informations de copyright
© 2021 The Authors. Angewandte Chemie published by Wiley-VCH GmbH.
Déclaration de conflit d'intérêts
The authors declare no conflict of interest.