Bimetallic Aluminum- and Niobium-Doped MCM-41 for Efficient Conversion of Biomass-Derived 2-Methyltetrahydrofuran to Pentadienes.
2-Methyltetrahydrofuran
Cleavage of C−O Bond
Niobium Sites
Pentadienes
Journal
Angewandte Chemie (Weinheim an der Bergstrasse, Germany)
ISSN: 0044-8249
Titre abrégé: Angew Chem Weinheim Bergstr Ger
Pays: Germany
ID NLM: 100955692
Informations de publication
Date de publication:
19 Dec 2022
19 Dec 2022
Historique:
received:
17
08
2022
medline:
19
12
2022
pubmed:
19
12
2022
entrez:
20
3
2024
Statut:
ppublish
Résumé
The production of conjugated C4-C5 dienes from biomass can enable the sustainable synthesis of many important polymers and liquid fuels. Here, we report the first example of bimetallic (Nb, Al)-atomically doped mesoporous silica, denoted as AlNb-MCM-41, which affords quantitative conversion of 2-methyltetrahydrofuran (2-MTHF) to pentadienes with a high selectivity of 91 %. The incorporation of Al The highly selective conversion of biomass‐derived 2‐methyltetrahydrofuran (2‐MTHF) into pentadienes has been achieved over an aluminum and niobium bimetallic atomically doped MCM‐41. The Nb
Autres résumés
Type: Publisher
(ger)
The highly selective conversion of biomass‐derived 2‐methyltetrahydrofuran (2‐MTHF) into pentadienes has been achieved over an aluminum and niobium bimetallic atomically doped MCM‐41. The Nb
Identifiants
pubmed: 38505214
doi: 10.1002/ange.202212164
pii: ANGE202212164
pmc: PMC10946597
doi:
Types de publication
Journal Article
Langues
eng
Pagination
e202212164Informations de copyright
© 2022 The Authors. Angewandte Chemie published by Wiley-VCH GmbH.
Déclaration de conflit d'intérêts
The authors declare no conflict of interest.